Cu-Mn-Zr复合催化剂制备及其催化氧化乙酸乙酯性能-中国环境科学.PDFVIP

中国环境科学 2018,38(8) ：2927~2933 China Environmental Science Cu-Mn-Zr 复合催化剂制备及其催化氧化乙酸乙酯性能 张菊茹,李济吾* (浙江工商大学环境科学与工程学院,浙江 杭州 310012) 摘要：采用溶胶凝胶法制备了 4 种不同金属摩尔比的 Cu-Mn-Zr 复合催化剂,利用 BET 、XRD 和 XPS 对其进行了表征分析,通过固定床管式反应器评 价了其对乙酸乙酯模拟气体的催化活性,定性测定了其催化反应降解产物.结果表明,Mn 的加入增大了催化剂的比表面积和总孔容,催化剂的 N2 吸附- 解吸等温线为 IV 型.Cu-Zr(1:1)催化剂观察到氧化铜晶体和四方晶型氧化锆晶体,氧化铜晶体随着 Cu 比例的减小而降低,Mn 的加入导致氧化锆晶体消 失.催化剂无固定形态,呈现良好的分散性.增大 Mn/Zr 摩尔比能提高催化活性.Cu-Mn-Zr 的适当组分比能提高其低温催化活性,其中 Cu-Mn-Zr(1:1:1) 催化剂的低温催化活性与 CO2 的选择性较佳,在 200℃时对 CO2 的选择性达到 96.7%.降解产物分析表明,乙酸乙酯降解中间产物有乙酸和乙醇,最终降 解产物主要有 CO 和 H O 等. 2 2 关键词：Cu-Mn-Zr 催化剂；催化氧化；乙酸乙酯；活性；溶胶凝胶 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2018)08-2927-07 * Preparation of Cu-Mn-Zr composite catalyst and performance for catalytic oxidation of ethyl acetate. ZHANG Ju-ru, LI Ji-wu (School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China). China Environmental Science, 2018,38(8)：2927~2933 Abstract ：The new Cu-Mn-Zr composite catalyst with four molar ratios of different metals was prepared by sol-gel method. The catalysts were characterized by BET, XRD and XPS. The catalytic activity of Cu-Mn-Zr composite catalyst on the simulated gas of ethyl acetate was evaluated by a fixed bed tube reactor. The degradation products of the catalytic reaction were detected qualitatively. Addition of Mn significantly increases the specific surface area and total pore volume of the catalyst. The N2 adsorption-desorption isotherm of the catalyst is type IV. Copper oxide crystals and tetragonal zirconia crystals in the Cu-Zr (1:1) catalyst were observed. The copper oxide crystals decreased with the decrease of Cu rati