一种解毒健脾中药驱除有毒重金属的机理研究-环境科学.PDFVIP

1999 5 ENVIRONMENTAL SCIENCE May, 1999 * 朱志良　乔俊莲　陆国弟　陈与德 孙爱贞 (, 200092E-mail:zzl mail.tongji.edu.cn) ( , 200032) 38.50. 1,0. 1,pH ,pH .pH ,, EDTA-Zn ,Zn . . , , ,pH , , . Mechanism Study of One Kind of Antidotal Traditional Chinese * Medicine on Excluding Poisonous Heavy Metals Zhu ZhiliangQiao JunlianLu GuodiChen Yude (Dept. of Chemistry, Tongji University, Shanghai200092, China E-mail:zzl mail.tongji.edu.cn) Sun Aizheng (Shanghai Chinese Medicine University, Shanghai200032) Abstract A pH-potentiometric titration method was used to determine theacid dissociation constants of thean- tidotal traditional Chinese medicine at 38.50.1 and ionic strength I = 0. 1. The stability constants of the 2+ 2+ 2+ complexes of this medicine with Pb ,Cd , Hg were also determined. T he distribution of complexes of this 2+ 2+ 2+ antidotal Chinese medicinewith Pb ,Cd ,Hg at different pH were obtained. It was found that this medicine - . has a better effect for excluding theheavy metal ions in human boby than EDTA Zn salt The excluding mecha- nism of above heavy metal ions with this medicine was discussed on the opinion of coordination chemistry. , , , - , , Keywords Chinese medicine detoxify heavy metal pH potentiometric titration stability constants coordi- nation chemistry. , . 1, 2-(BAL) , [ 1,2] . . ( , , 03 ) , , [3,4]