塑胶基质对木材塑胶复合材户外耐候性质之影响-中兴大学森林系.PDF

林產工業30(3) ：135～147(2011)研究論文 135 塑膠基質對木材塑膠複合材戶外耐候性質之影響 1 1 1 2 李家皇 吳東霖 洪克昌 吳志鴻 【摘要】本研究除利用高密度聚乙烯 （High density polyethylene, HDPE ）、回收型高密度聚乙烯（Recycled high density polyethylene, rHDPE ）、低密度聚乙烯（Low density polyethylene, LDPE ）、聚丙烯（Polypropylene, PP ）及 聚苯乙烯 （Polystyrene, PS ）5 種不同塑膠基質與山黃麻木粒片製備木材塑膠複合材（Wood–plastic composites, WPC ）之外 ，並比較此5 種複合材經48 週戶外耐候試驗後之各項性質差異性。試驗結果顯示，各複合材之抗彎 強度及抗彎彈性模數均隨著耐候時間增加而下降 ，其中HDPE 、rHDPE 及PP 所製備之木材塑膠複合材具有較高 之抗彎強度及抗彎彈性模數保留率 ；相對的，LDPE 及PS 所製備者則較低 。另一方面，由傅立葉轉換紅外線光 譜儀分析結果發現，以PP 所製備之 WPC ，其表面羰基指數增加之幅度最大，而利用 HDPE 、rHDPE 及 LDPE 所製備之WPC ，羰基指數變化量則呈現先上升後下降之現象。此外，比較HDPE 與rHDPE 所製備之WPC ，兩 者具有相似之抗彎及耐候性質，顯示回收型高密度聚乙烯實具有應用於木材塑膠複合材之潛能。 【關鍵詞】木材塑膠複合材、塑膠基質、戶外耐候、強度保留率、羰基指數。 Effects of Plastic Matrix on Outdoor Weathering Properties of Wood–plastic Composites Chia-Huang Lee1 Tung-Lin Wu1 Ke-Chang Hung1 Jyh-Horng Wu2 【Abstract 】The purpose of this work is to compare the mechanical behavior and weathering properties of different types of wood–plastic composites (WPC), including virgin high density polyethylene (HDPE), recycled high density polyethylene (rHDPE), virgin low density polyethylene (LDPE), virgin polypropylene (PP) and virgin polystyrene (PS) based WPCs, during 48 weeks of outdoor weathering. Results revealed that the modulus of rupture (MOR) and modulus of elasticity (MOE) of all WPCs decreased with increasing exposure time. Of these, the HDPE, rHDPE and PP based composites showed the higher MOR and MOE retention ratios after 48 weeks of outdoor weathering, while the LDPE and PS based WPCs had the lower values. On the other hand, Fourier transform infrared (FTIR) spectra demonstrated that the PP based WPC ex