化学反应工建英文课件Chapter6.ppt

化 学 反 应 工 程 Over what range of conversions are the plug-flow reactor and MFR volumes identical? What conversion will be achieved in a MFR that has a volume of 90 L? What plug-flow reactor volume is necessary to achieve 70% conversion? What MFR reactor volume is required if ‘effluent from the plug-flow reactor in part (c) is fed to a MFR to raise the conversion to 90%? If the reaction is carried out in a constant-pressure batch reactor in which pure A is fed to the reactor, what length of time is necessary to achieve 40% conversion? Plot the rate of reaction and conversion as a function of PFR volume. Cri’tique the answers to this problem. 化 学 反 应 工 程 For the extremes of negligible and infinite recycle the system approaches plug flow and mixed flow, or R = 0 R = ∞ Plug flow mixed flow The approach to these extremes is shown in Fig. 6.15. 化 学 反 应 工 程 Figure 6.15 The recycle extremes approach plug flow and mixed flow . 化 学 反 应 工 程 Figure 6.16 and 6.17 show the transition from plug to mixed floe as R increases, and a match of these curves with those for N tanks in series (Figs.6.5 and 6.6) gives the following rough comparison for equal performance: ? ? ? 1.0 2.8 7.5 0.5 1.4 2.9 0.33 0.90 1.7 0.11 0.29 0.5 0 0 0 ? ? ? 1.0 2.2 5.4 0.5 1.1 2.1 0.33 0.68 1.3 0.11 0.22 0.36 0 0 0 at XA =0.5 0.90 0.99 at XA=0.5 0.90 0.99 R for second-order reaction R for first-order reaction No. of tanks 1 2 3 4 10 ? 化 学 反 应 工 程 Figure 6.16 Comparison of performance of recycle and plug flow for first-order reactions . 化 学 反 应 工 程 Figur