利用废弃牛皮纸和瓦楞纸制备纤维增强包装材料-包装工程.PDF

包装工程摇 PACKAGING ENGINEERING Vol.34 No.32013鄄02 摇摇摇摇 8 利用废弃牛皮纸和瓦楞纸制备纤维增强包装材料 1 1,2 1 3 张然然 ,李大纲 ,王海莹 ,唐 翔 (1.南京林业大学,南京210037;2.南京林业大学 现代分析测试中心,南京210037;3.国家知识产权专利局, 北京 100088) 摘要:采用化学法并结合机械法,制得了形貌尺寸均匀的生物质纤维素微纳米纤丝,并将其制备成膜,观察了 其微观结构,测试了纳米纤维素膜的相关性能。 结果表明:废弃牛皮纸和瓦楞纸经过处理,可以制得纳米微晶 纤维素,直径为30~100 nm;同时再生膜具有较高的强度,牛皮纸和瓦楞纸的拉伸强度分别为107.4,121.81 MPa,弹性模量分别为5.6,5.2 GPa,纳米纤维素膜的拉伸强度分别是牛皮和瓦楞原纸的5倍和8倍;对2种废 弃材料进行均质和离心处理,可以显著提高其性能。 关键词:废弃牛皮纸;废弃瓦楞纸;纤维增强;包装材料 中图分类号:TB484.1;TB487摇 文献标识码:A摇 文章编号:1001鄄3563(2013)03鄄0008鄄04 Preparation of Nanofiber Reinforced Packaging Material Using Waste Kraft Paper and Corrugated Paper 1 1,2 1 3 ZHANGRan鄄ran ,LI Da鄄gang ,WANGHai鄄ying ,TANGXiang (1.Nanjing Forestry University of Wood Science and Technology,Nanjing210037,China;2.Advanced Analysis and Testing Center of NanjingForestry University,Nanjing210037,China;3.ThePatent Officeof SIPO,Beijing 100088, China) Abstract:We obtained biomass cellulose micro/ nano fiber with uniform dimension using chemical and mechanical methods and preparedfilm,then observed their microscopic structure and tested performance of the nanofiber films. The results showed that cellulose nanofibers can be obtained after processing,with the diameter between 30 nm and 100 nm,and the nanofiber films exhibitshigher strength;thetensile strengthof thekraftpaper andthecorrugatedpa鄄 per are 107.4 MPa and 121.8 MPa;their elasticmodulusare5.6 GPaand5.2 GParespectively. Meanwhile,tensile strengthofthenanofiberfilmsis5timesand8timeshigherthanthatofthebasepaper. Italsodemonstratedthathomo鄄 geneous and centrifugal treatment can increase performance of the material significantly. Key words:waste kraft paper;waste corrugated paper;fiber reinforced;packaging material 摇 摇 生物质纤维素是地球上大量存在的天然高分子