含铟硫酸浸出液中铟的富集-中国有色金属学报.PDF

第18 卷专辑1 中国有色金属学报 2008 年6 月 Vol.18 Special 1 The Chinese Journal of Nonferrous Metals Jun. 2008 文章编号：1004-0609(2008)S1-0121-05 含铟硫酸浸出液中铟的富集 1 1 2 1 1 俞小花 ，谢 刚 ，李永刚 ，刘春侠 ，刘 康 (1. 昆明理工大学 材料与冶金学院，昆明650093；2. 云南冶金集团总公司 技术中心，昆明650031) 摘 要：提出从含铟硫酸溶液中富集铟的试验方案：焙砂预中和—硫化锌精矿还原—石灰石中和沉铟。在一定的 实验条件下确定各个工序的最佳条件：焙砂用量为理论量的1.3 倍，预中和后溶液的酸度大约降至6 g/L ；硫化锌 精矿的用量为理论量的2.2～2.3 倍，还原后溶液中Fe3+ 的浓度大约降至0.5 g/L ；石灰石的用量为理论量的2.0 倍， 沉铟后溶液中In3+ 的浓度降至1 mg/L 以下。在此最佳条件下，可使沉铟渣中铟的品位达到0.1% 以上。 关键词：铟；预中和；还原；中和沉铟 中图分类号：TF 843.1 文献标识码：A Enriching indium from sulfuric acid leaching solution bearing high content of indium 1 1 2 1 1 YU Xiao-hua , XIE Gang , LI Yong-gang , LIU Chun-xia , LIU Kang (1. Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Technology Center of Yunnan Metallurgy Group Co., Kunming 650031, China) Abstract: The process of calcine preneutralization-zinc concentrate reduction-limestone neutralization for indium precipitation from pressure leaching of zinc concentrate with different indium contents was investigated. Under a certain experimental condition, the optimal condition in every procedure was put forward. The dosage of calcine is 1.3 times of theoretic value, and the concentration of solution is about 6 g/L; the dosage of zinc sulfide mineral concentrate is 2.2−2.3 times of theoretic value, and Fe3+ concentration o