纳米氧化铅的制备及表面酸碱性质.PDF

24 2 () Vol. 24 No. 2 2010 4 JOURNAL OF UN IVERSITY OF JINAN ( Sc.i Tech) Apr. 2010 : 1 71- 3559( 2010) 02- 0123- 04 纳米氧化铅的制备及表面酸碱性质 郭 英, 张 琦, 孙国新, 孙中溪 ( , 250022) : 采用均匀沉淀- 煅烧法制备纳米 PbO, 利用氮气吸附等温线( BET)X 射线衍射( XRD)和透射电镜( TEM ) 对其 进行 征; MEDUSA 软件模拟 Pb- O- H O体系中不同组分的分布情况; 用酸碱滴定技术考察纳米 PbO 面的酸碱性质结 2 果 明, 所制 PbO 样品的粒径在 80 nm 左右, 其悬浮液的缓冲能力随着 PbO 加入量的增多明显增强, 样品 面在水溶液中有 非常明显的酸碱性质经 Zeta 电位测定氧化铅零电点出现时, pH = 9. 8 : 纳米 PbO; 面酸碱性质; Zeta 电位 : TB383 : A Syn thesis and Surface A cidBase P rop erties of PbO N anoparticles GUO Y ing, Z HANG Q ,i SUN G uoxin, SUN Zho ngx i ( School of Chem istry and Chem icalEngineering, University of Jinan, Jinan 250022, China) A bstrac t: PbO nanoparticlesw ere achieved by hom ogeneous precip itationcalcination m ethod and characterized using n itrogen ad sorption isotherm s, Xray d iffraction and transm ission electron m icroscope. The d istribu tion of d ifferen t components in PbOH O system 2 w as smi u lated by usingMEDUSA software; the acidbase properties and zeta potential of PbO nanoparticlesw ere studied. The testing re su lts show that the particle size of synthesized PbO is abou t 80 nm; the su rface of PbO possesses obvious acidbase property; w ith in creasing the amount of PbO in the suspension, the pH buffer capacity of solution increases dram atically. The zeropoint charge of PbO is determ ined to be at pH = 9. 8. K ey w ord s: PbO nanoparticle; surface acidbase property; zeta potential , ,