溴化N-辛烷异喹啉在盐酸溶液中对Q235碳钢的缓蚀行为.PDF

第36 卷 第3 期 中国腐蚀与防护学报 Vol.36 No.3 2016 年6 月 Journal of Chinese Society for Corrosion and Protection Jun. 2016 溴化N-辛烷异喹啉在盐酸溶液中对Q235 碳钢 的缓蚀行为 王春霞 陈敬平 张晓红 王赪胤 扬州大学化学化工学院 扬州 225002 摘要：采用失重法、动电位极化曲线法和电化学阻抗谱研究了溴化N- 辛烷异喹啉([C iQuin]Br) 在盐酸介质中 8 对Q235 碳钢的缓蚀行为。结果表明：[C iQuin]Br 是一种同时抑制阳极和阴极反应的混合型缓蚀剂，缓蚀效率 8 随缓蚀剂浓度增大而增大，随温度的升高而降低；[C iQuin]Br 在Q235 碳钢表面的吸附符合Laugmuir 等温吸附 8 式，吸附平衡常数Kads 值较大，说明缓蚀剂在金属表面的吸附能力较强。 关键词：碳钢 缓蚀剂 溴化N-辛烷异喹啉 腐蚀速率 缓蚀效率 吸附 中图分类号：TG 174.42 文献标识码：A 文章编号：1005-4537(2016)03-0245-08 Corrosion Inhibition of Octyl Isoquinolinium Bromide on Q235 Carbon Steel in HCl Solution WANG Chunxia, CHEN Jingping, ZHANG Xiaohong, WANG Chengyin College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China Abstract: The corrosion inhibition of octyl isoquinolinium bromide on Q235 carbon steel in HCl solution was studied by means of mass loss test, potentiodynamic polarization curves and electro- chemical impedance spectroscopy. The results show that octyl isoquinolinium bromide is a mix- type inhibitor which can inhibit the anodic- and cathodic- reactions. The inhibition efficiency in- creases with the concentration of inhibitor and decreases with temperature. The adsorption of octyl isoquinolinium bromide on Q235 carbon steel surface accords with Laugmuir isothermal adsorp- tion. The adsorption equilibrium constant Kads is big, which can explain the strong ads