石煤酸浸提钒过程中V、Fe、Al的浸出行为研究.docVIP

doi：10.3969/j.issn.1007-7545.2016.06.014石煤酸浸提钒过程中V、Fe、 doi：10.3969/j.issn.1007-7545.2016.06.014 李道1,2，刘涛1,2,3，张一敏1,2,3，黄晶1,2,3，孙坤1,2，汪博1,2 （1.武汉科技大学 资源与环境工程学院，武汉 430081； 2.湖北省页岩钒资源高效清洁利用工程技术研究中心，武汉 430081； 3.钒资源高效利用湖北省协同创新中心，武汉 430081） 摘要：在热力学计算分析的基础上，对某云母型石煤脱碳样在酸浸提钒过程中V、Fe、Al的浸出行为进行研究。结果表明，在氟化钙—硫酸浸出体系中，含钒矿物白云母溶解的同时，赤铁矿和钾长石等矿物亦会发生溶解反应，硫酸浓度、浸出温度、浸出时间、液固比等参数对V、Fe、Al的浸出率影响有相同趋势，铝浸出率高于钒和铁；酸浸过程中主要矿物溶解的难易顺序为赤铁矿、白云母、钾长石，且赤铁矿达到溶解平衡所需时间较长，而白云母和钾长石可在较短时间内达到溶解平衡；要减少酸浸提钒过程中铁的溶出，可在保证钒浸出率的前提下适当缩短浸出时间。 关键词：石煤；酸浸；V；Fe；Al；浸出行为；热力学 中图分类号：TF841.3 文献标志码：A 文章编号：1007-7545（2016）06-0000-00 Leaching Behaviour of V, Fe, Al during Vanadium Extraction from Stone Coal by Sufuric Acid Leaching LI Dao1, 2, LIU Tao1, 2, 3, ZHANG Yi-min1, 2, 3, HUANG Jing1, 2, 3, SUN Kun1, 2, WANG Bo1, 2 (1. College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China; 2. Hubei Province Engineering Technology Research Center of High Efficient Cleaning Utilization for Shale Vanadium Resource, Wuhan 430081, China; 3. Hubei Province Collaborative Innovation Center for High Efficient Utilization of Vanadium Resources, Wuhan 430081, China) Abstract：Leaching behaviours of vanadium, iron and aluminum during vanadium extraction from stone coal were investigated applying decarburization sample of muscovite-type stone coal based on thermodynamics calculation and analysis. The results show that in calcium fluoride and sulfuric acid leaching system, potassium feldspar and hematite would be dissolved accompanied with dissolution of main vanadium-bearing mineral muscovite. The effects of sulfuric acid concentration, leaching temperature, leaching time, and ratio of liquid to solid on leaching rates of vanadium, iron, and aluminum present the same trend. Leaching rate of aluminum is higher than those of vanadium and iron. During vanadium extraction from stone coal decarburization sample, main minerals are sequenced in terms of leaching difficulty as hematite, muscovite, and