氨基磺酸中肉桂醛缩甲胺席夫碱的缓蚀行为研究-腐蚀科学与防护技术.PDF

第30 卷 第1 期 腐蚀科学与防护技术腐蚀科学与防护技术 Vol. 30 No. 1 2018 年1 月 CORROSION SCIENCE AND PROTECTION TECHNOLOGY Jan. 2018 氨基磺酸中肉桂醛缩甲胺席夫碱的 缓蚀行为研究 曾永昌 付朝阳 华中科技大学 材料化学与服役失效湖北省重点实验室 武汉 430074 摘要 合成了缓蚀剂肉桂醛缩甲胺席夫碱，并用傅里叶红外光谱仪对其进行定性检测。采用失重法、动电位极 化曲线、电化学阻抗谱(EIS) 和扫描电镜(SEM) 研究了该席夫碱在5% (质量分数) 氨基磺酸介质中对Q235 钢 的缓蚀行为。结果表明，肉桂醛缩甲胺席夫碱在70 ℃下具有很好的缓蚀效果，是一种混合型缓蚀剂，在Q235 钢表面的吸附符合Langmuir 等温式，主要为化学吸附。 关键词 席夫碱 缓蚀剂 Q235 钢 氨基磺酸 中图分类号 TG 174 文章编号 1002-6495(2018)01-0021-06 Inhibition Performance of N-cinnamylidene Methylamine Schiff-base for Q235 Steel in Sulfamic Acid ZENG Yongchang, FU Chaoyang Key Laboratory of Materials Chemistry Service Failure of Hubei Province, Huazhong University of Science and Technology, Wuhan 430074, China Correspondent: FU Chaoyang, E-mail: cyfu@ Manuscript received 2017-03-08, in revised form 2017-04-27 ABSTRACT The corrosion inhibitor N-cinnamylidene methylamine Schiff-base was synthesized. The synthetic product was qualitatively detected by Fourier transform infrared spectroscopy (FTIR). The inhibi- tion performance of N- cinnamylidene methylamine Schiff- base on the corrosion of Q235 steel in 5% (mass fraction) sulfamic acid solution was studied by weight loss, electrochemical impedance spectrosco- py (EIS), potentiodynamic polarization and scanning electron microscope (SEM). The results showed that the Schiff-base had a good inhibition effect at 70 ℃, and it was a mixed-type corrosion inhibitor. The ad- sorption of the Schiff-base