纳米线染料敏化太阳能电池-.pptxVIP

20/7/1969Thats one small step for (a) man, one giant leap for mankind---Neil Alden ArmstrongMaterials science and engineering do ?To create new materials or improve the performance of the current materialsStep by step, small but essentialNanowire dye-sensitized solar cellsMATT LAW1,2*, LORI E. GREENE1,2*, JUSTIN C. JOHNSON1, RICHARD SAYKALLY1 ANDPEIDONG YANG1,2?Nature 2019报告人：Mr 齐E-mail: wildqisina目 录1. 研究背景2. 研究目的3. 工作创新4. 材料制备5. 结果和讨论6. 总结和展望7. 理想很丰满，现实很骨感Background——（4/16)To improve the efficiencies of DSCs.Considerable efforts have been made to develop dyes and dye mixtures that absorb better at long wavelengths, so far with little success. Disadvantages of TiO2 nanoparticle films:1 trap-limited diffusion for electron transport——a slow mechanism2 high rate of defects ——consequently high recombinationAnother option for improving the absorption of red and near-infrared light—thickening the nanoparticle film to increase its optical density—is unsuccessful because the film thickness comes to exceed the electron diffusion length through the nanoparticle network.（膜的厚度超过了电子扩散长度）额， 我死了A B thicknessHighlights——(5/16)What we do?Replacing the traditional nanoparticle film with a dense array of oriented, crystalline ZnO nanowires.Electron transport in crystalline wires is expected to be several orders of magnitude faster than percolation through a random polycrystalline network.（纳米线中电子传输速率要高几次方）Synthesis and preparation——(6/16)Synthesis ——Two steps:1 10–15-nm-thick film of ZnO quantum dots was deposited onto F:SnO2 conductive glass (FTO)substrates by dip coating.2 Wires were grown from these nuclei through the thermal decomposition of a zinc complex.Results and discussion——(7/16)Properties of nanowire filmPhysical:1 Single crystalline2 Dense arraysHigh aspect ratioActive surface area 1/5 as large as a nanoparticle cellHow to boost the aspect ratio ?Results and discussion——(8/16)Using polyethylenimine (PEI)（聚乙烯亚