稀土对水泥熟料矿物形成的作用-中国科技论文在线.PDF

硅酸盐通报 　1996 年第 5 期 稀土对水泥熟料矿物形成的作用 苏达根　　杨东生　　黄其秀 (华南理工大学无机材料系 　广州 510641) 摘 　　要 稀土元素氧化物于 0. 2～2. 0 ×10 - 4 的微量范围内可改善水泥生料的易烧性 , 降低熟料中游离氧化钙含 量 ,增加阿利特含量。在该微量范围内 ,随着稀土含量增加 ,其作用相应增强 ;但超过 2. 0 ×10 - 4 后 ,即使稀土 元素氧化物含量增至 1. 0 ×10- 3 , 其作用增幅亦不大。煅烧温度于 1300 ℃以下 , 稀土的作用甚弱 , 而于 1350 ℃至 1400 ℃时其作用较显著。不同种类的稀土元素对水泥熟料矿物形成的作用有差别 ,镧系元素的作 用优于非镧系元素的稀土元素 ;稀土元素富集于熟料中间相 ,镧系元素尤为明显。 关键词 :稀土元素 ,水泥 ,熟料 The Effect of Rare Earth Elements on Cement Clinker Formation S u Dagen 　　Yang Don gshen g 　　Huan g Qixiu ( South China University of Technology) Abstract Rare earth elements in a microrange of 0. 2 ～2. 0 ×10- 4 are totally capable of improving the burnability of portland cement , reducing the fCaO and increasing the alite content in the clinker. While the rare earth content varies in this microrange , the effect gets stronger clearly with increasing proportion of rare earth elements. Yet , af ter that , even their content is increased to 10 ×10 - 4 its effect of benefit does not grow much. The effect of rare earth elements would be still faint when the calcination temperature is lower than 1300 ℃, but that will get obvious at 1350 ℃～1400 ℃. There are differences in the effects on cement clinker formation due to various types of rare earth elements. Lanthanide prevails over rare earth elements of nonlanthanide. The rare earth elements are dis tributed mainly over interstitial phases of clinker. Key words : rare earth elements , cement , clinker 1. 引 　　言 料矿物中的分布 ,及对熟料矿物组成结构的 以含微量镧系元素的粘土或工业废渣作