芳香环状聚膦酸酯齐聚物的基质辅助激光解吸电离飞行时间-分析化学.PDF

29 ( FENXI HUAXUE) 11 2001 11 Chi ese Jour al of A alytical Chemistry 1303~ 1306 张红明季怡萍陈天禄* ( 中国科学院长春应用化学研究所, 高分子物理与化学国家重点实验室, 长春 130022) 1, 8, 9- , , , , , , 1 1995 McGill Hay 1, 2- 1 2~ 4 5 , : , , 6 Hay , 1, 8, 9-, , , , 1, 8, 9- , -- 4-, , 4 , , 2 2. 1 , 16--3- , , , ( 3a) ( 3b) ( 3c) ( 3d) 2. 2 LDI- 1700 -( Li ear Scie tific ) , N , 337 2 m,3 s, 1 10- 4 Pa, - 4. 75 kV, ( A , 2000-12-30 ; 2001-04-27 1304 29 C H O ) 1, 8, 9-2, 5-, CHCl 20 28 2 3 , N, N-, 12 gL5 gL 5 gL, 3 ( 3b) 1 1 ( 3b) Table 1Matrix-assisted laser desorptio io izatio time-of-flight mass spectrometric (MALDI-TOF-MS) data of cyclic oligomer ( 3b) [M + H] + [M + Li] + ( n ) ( mz ) ( Da) a ( Da) b ( mz ) ( Da) a ( Da) b Degree of polymerizatio Si gal Mass umber Deviatio Si gal Mass umber Deviatio 2 702. 0 701. 6 - 1 708. 4 707. 6 + 1 3 1054. 8 1051. 8 + 3 1059. 7 1057. 8 + 2 4 1401. 6 1402. 1 - 1 1409. 5 1408. 1 + 1 5 1753. 2 1752. 5 + 1 1760. 8 1758. 2 + 2 6 2106. 7 2102. 2 + 4 2112. 2 2108. 7 + 4 a. [M + H] + [M + Li] + ( the average molecular weight calculated for [M + H] + or [M + Li] +