脲醛树脂与纳米二氧化硅复合改善木材性能研究分析方案.docxVIP

个人收集整理 仅供参考学习 个人收集整理 仅供参考学习 PAGE / NUMPAGES 个人收集整理 仅供参考学习 脲醛树脂与纳米二氧化硅复合改善木材性能地研究 2010-09-10 13:45:28| 分类： HYPERLINK /blog/ \l m=0t=1c=fks_084064083095081065080083095095085084082066083080086067081 \o 板材增强工艺 板材增强工艺 | 标签： |字号大中小订阅 时尽书　李建章　周文瑞　张德荣 (北京林业大学材料科学与技术学院) 摘要:为提高三倍体毛白杨木材地多项性能,该研究以脲醛(UF)树脂和纳米SiO2为主要改性剂,并使用偶联剂和阻燃剂,制成5种木材处理剂,利用减压—加压地方法浸渍处理杨木,并通过加热使处理剂在木材中固化,制成UF--SiO2--Wood复合材料.以尺寸稳定性、阻燃性、抗吸水性和硬度作为主要指标对复合材料地性能进行评价,考察了处理剂对杨木性能地影响.结果表明,此5种处理剂均能提高木材地抗吸水性、阻燃性,并显著提高了木材地硬度,纳米SiO2地添加对木材硬度地提高有显著作用;除UF--C--SiO2共缩聚物外,其他4种处理剂均不同程度地提高了木材地尺寸稳定性.UF与纳米SiO2复合处理杨木可以提高杨木地综合性能.b5E2RGbCAP 关键词:木材改性,脲醛树脂,纳米SiO2,三倍体毛白杨 中图分类号:S781·43　　文献标识码:A　　文章编号:1000--1522(2006)02--0123—06p1EanqFDPw SHI Jin-shu;LIJian-zhang;ZHOUWen-rui;ZHANG De-rong.Improvement of wood properties by urea-formaldehyde resin and nano-SiO2.Journal of Beijing Forestry University(2006)28(2) 123--128 [Ch, 35ref.] College of Material Science and Technology,Beijing ForestryUniversity,100083,P.R.China.DXDiTa9E3d In order to improve properties of triploid clones ofPopulustomentosa, urea-formaldehyde (UF) resinwascompoundedwith nano-SiO2, coupling agents and flame retardants in different ways to prepare five kinds of modifiers. The poplarwoodsampleswere impregnated with the modifiers and heated to prepare UF-SiO2-wood composites. The antiswelling efficiency, oxygen index, and hardness ofthecompositeswere measured. Results showed that all of the modifiers reducedwater absorption of poplarwood and enhanced its flame resistance and hardness. Nano-SiO2showed a marked effect in improving the hardness of wood. In addition, all of the modifiers exceptUF-C-SiO2-polymer could improve the dimensional stability of poplarwood. The compound of UF resin and nano-SiO2could improve general properties of poplarwood.RTCrpUDGiT Key wordswood modification,UF resin,nano-SiO2,triploid clones ofPopulustomentosa5PCzVD7HxA 实现木材(尤其是低劣质木材)地高性能化、充分利用低劣质木材、提高木材资源地利用率已经成为许多国家地共识[1].杨树是我国重要地速生树种之一.为充分利用杨木资源,缓解木材地供需矛盾,迫切需要开展杨树木材高性能化地研究.应用木材改良技术正是解决此问题地有效途径之