粗铅电解废液萃取提锌循环利用工艺研究.docVIP

doi：10.3969/j.issn.1007-7545.2012.07.003 doi：10.3969/j.issn.1007-7545.2012.07.003 何静，王涛，黄玲，罗超，王小能 （中南大学 冶金科学与工程学院，长沙 410083） 摘要：采用“硫酸沉铅—中和—P204萃取提锌—硫酸反萃”工艺净化处理铅电解废液，重点考察P204煤油体系萃取提锌、硫酸反萃及萃取反萃循环过程。结果表明，按照相比1∶1.5单级萃取的萃取率可达99%左右，3 mol/L硫酸单级反萃锌反萃率基本可达100%。9次萃取反萃循环试验后，锌富集浓度可达33 g/L，负载有机相锌反萃率达到99.49%，锌直收率可达88.24%。 关键词：铅电解液；锌；P204；萃取；反萃 中图分类号：TF813；TF812 文献标识码：A 文章编号：1007-7545（2012）07-0000-00 Study on Zinc Extraction from Crude Lead Electrolyte HE Jing, WANG Tao, HUANG Ling, LUO Chao, WANG Xiao-neng (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China Abstract：The process of lead precipitating with H2SO4, neutralization, zinc extraction with P204, stripping with H2SO4 was proposed for lead electrolyte purification. The process of zinc extraction with P204+kerosene system, back extraction with H2SO4 and cyclic process of extraction-back extraction were investigated emphatically. The results show that the single stage extraction rate is about 99% on condition of O/A=1/1.5. Back extraction rate of zinc single stage is about 100% with 3 mol/L H2SO4. The enriched zinc concentration is 33 g/L, zinc stripping rate reaches 99.49%, and zinc total recovery rate is about 88.24% after 9 times extraction-back extraction cyclic process. Key words: lead electrolyte; zinc; P204; extraction; stripping 铟是一种稀散金属，分布分散，少见独立铟矿物，多伴生在锌等重有色金属矿之中，铟常作为重有色金属副产品得到回收 ADDIN EN.CITE EndNoteCiteAuthor王树楷/AuthorYear2006/YearRecNum201/RecNumDisplayText[1]/DisplayTextrecordrec-number201/rec-numberforeign-keyskey app=EN db-id=0p5apvds95wt9dev923vvza0sapexetdda5a201/key/foreign-keysref-type name=Book6/ref-typecontributorsauthorsauthorstyle face=normal font=default charset=134 size=100%王树楷/style/author/authors/contributorstitlestitlestyle face=normal font=default charset=134 size=100%铟冶金/style/title/titlessectionstyle face=normal font=default size=100%36/stylestyle face=normal font=default charset=134 size=100%-56/style/sectiondatesyear2006/year/datespub-location