紫外分光光度法同时测定乙醛和乙二醛.PDFVIP

31 1 Vol. 31, No. 1 2010 2 Journal of Hebei University of Science and T echnology eb.2010 : 1008-1542( 2010) 01-0022- 03 1 2 1 1 1 1 刘树彬 , 杨建一 , 张星辰 , 陆 敏 , 武 戈, 陈 凯 ( 1. 石家庄学院化工学院, 河北石家庄 050035; 2. 河北科技大学理学院, 河北石家庄050018) : 利用醛与水合肼反应生成腙, 采用紫外分光光度 可间接分析乙醛和乙二醛的含量成腙 条件为n( 醛基) n( 肼) [ 1 2, pH 值为5. 5( 用醋酸-醋酸钠缓冲溶液调节) , 温度为60 e , 时间 为50 min, 检测波长为230 nm 和280 nm测得 230 nm 和 280 nm 处的相对标准偏差分别为 1. 50%和1. 89% , 乙醛和乙二醛的平均回收率分别约为103. 53 % 和97. 14%该方 可用于乙醛 硝酸氧化 制备乙二醛中乙醛和乙二醛含量的监测 : 乙醛; 乙二醛; 水合肼; 腙; 紫外分光光度 : O657. 2 :A UV-spectrophotometric determination of both acetaldehyde and oxalaldehyde 1 2 1 1 1 1 LIU Shu-bin , YANG Jian-yi , ZHANG Xing-chen , LU Min , WU Ge , CHEN Kai ( 1. School of Chemical Engineering, Shijiazhuang College, Shijiazhuang H ebei 050035, China; 2. College of Sciences, H ebei University of Science and Technology, Shijiazhuang H ebei 050018, China ) Abstract: Based on the UV-spectrophotometry of hydrazone w hich w as obtained from aldehyde and hydrazine hydrate, the de- termination of acetaldehyde and oxalaldehyde at one time was proposed. The reaction was carried out at 60 e w ithin 50 minut- ess and the mol rat io of aldehyde group and hydrazine is not more than 1 B 2 and pH = 5. 5 ( regulated by CH COOH- 3 CH3 COONa buffer) . The detect w avelengths are 230 nm and 280 nm. The relative standard deviations under the wavelengths are 1. 50% and 1. 89% separately