有机磷农药多残留检测化学发光标记物的合成及鉴定-食品安全质量.PDFVIP

5 5 Vol. 5 No. 5 2014 5 Journal of Food Safety and Quality May. , 2014 1 1 1 1 1 1,2* 刘 涛 , 孟 超 , 姚 鑫 , 李景娜 , 程 燕 , 刘晓宇 (1. , 430070; 2. , 430070) 摘 要: 目的 O,O-, , 方法 O,O-, , 8 h , , 结果 , , BPCL , , 9000 mV结论 , 关键词: O,O-; ; ; Synthesis and identification of chemiluminescent markers used in the multi-residue determination of organophosphorus pesticides 1 1 1 1 1 1,2* LIU Tao , MENG Chao , YAO Xin , LI Jing-Na , CHENG Yan , LIU Xiao-Yu (1. College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070, China; 2. Key laboratory of Environment Correlative Dietology, Ministry of Education, Wuhan 430070, China) ABSTRACT: Objective Chemiluminescent markers were synthesized using O,O-diethylthiophosphoryl chloride and luminol for the multi-residue determination of organophosphorus pesticides. Methods Luminol and O, O-diethyl phosphoryl chloride were added to dichloromethane under ice-cooling with triethylamine as acid binding agent. After 8 h, the organic layer was separated and purified by column chromatography. Results The product was the chemiluminescent markers after indentation using UV and IR. It had a strong luminescent ability on the BPCL, and