试验装置和方法.pdf

电化学除铁用于建筑物的供水系统 吴星五, 高廷耀 ( 同济大学城市污染控制国家工程研究中心，上海200092) 摘 要：提出一种利用电化学除铁的水处理新技术，不需添加化学药剂且无二次污染，其作用机理是 利用阳极(不溶性)反应产生的新生态氧和溶解氧将Fe2+氧化成Fe3+ ，进而水解形成氢氧化铁胶体，再通过砂 滤去除。阴极反应生成的OH-引起pH值上升，提高了氧化速度；产生的微气泡促使高铁胶体集聚成较大的 颗粒，改善了过滤条件。电流密度越高除铁能力越强，但电流效率下降。试验采用的电流密度为 4.0mA/cm2 、 通电率为 50C/L，水流通 过单程处理，含铁量由 4.0mg/L 降至0.3mg/L 以下。采用循环处理方法可有效清除 水箱黄锈水，其耗电量≤0.02(kW·h)/m3，适用于城市建筑物的供水系统。 关键词：水处理；除铁；电化学　 中图分类号：TU991 文献标识码：A 文章编号：1000-4602(2002)06-0010-04 Iron Removal by Electrochemical Method for Water Supply System of 　 Buildings WU Xing　wu, GAO Ting　yao (National Engineering Research Center for Urban Pollution Control,Tongji Universi ty,　Shanghai 200092,China) Abstract ：A new electrochemical technology of water treatment for iron removal was propose d,which did not need any chemical agent and had no secondary pollution.The perfo rmance mechanism was electrolysis. Fe2+ was oxidized to Fe3+ by nascent oxygen and dissolved oxygen produced by anodic reaction (with dimensionally s table anodes),the Fe3+ was hydrolyzed to ferric hydroxide,and then the hyd rolysate was filtrated off by sand-bed filter.As pH increased due to the increas e of OH- formed by cathode reaction, the oxidation rate was increased.The ferr ic hydrocolloid particles were flocculated into much bigger flocs by small bubbl es produced during electrolysis process,so that the condition of filtration was improved.The higher the electrical charge passed per litter of water the high er the ability of iron removal,but the lower the current efficiency.The total ir on content was decreased from 4.0 mg/L to≤0.3mg/L,under the test conditions of current density 4.0mA/cm2,electrical charge per litter of water≥50 C/L (H2O),and single-pass operation,with quartz sand media adopted.Through circulating treatment,the rusty brown water in tank was cleaned efficie