d10(次外层电子)金属Cu(Ⅰ)配合物以结构多样化、具生物和医药活性和.doc

文章编号：201607013 2-(2-苯并咪唑基)-6-甲基吡啶铜(I)配合物( 曾雪花，，，，陈景林 （江西理工大学冶金与化学工程学院江西 赣州 341000） 摘 要：′-双(二苯基膦)(dppf)、2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)和[Cu(CH3CN)4](ClO4)作为起始原料，合成铜(I)[Cu(Hbmp)(dppf)](ClO4) (1)．X-射线单晶衍射表明：配合物1核配合物，采用四配位方式，分别与个和个原子连接一个四面体，而电荷转移跃迁(MLCT) 关键词：铜；双膦配体；双核配合物晶体结构 中图分类号：TF811 文献标识码：A 2-(2-benzimidazolyl)-6- methylpyridine Cu(I)Fe(II) heterodinuclear complex ZENG Xue-hua, LUO Yan-sheng, DI Bao-sheng, XIA Yong, QIU Lu, CHEN Jing-lin (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China) Abstract: A Cu(I)Fe(II) heterometallic dinuclear complex [Cu(Hbmp)(dppf)](ClO4) (1) was synthesized by using 1,1′-bis(diphenylphosphino)ferrocene (dppf), 2-(2-benzimidazolyl)-6-methyl pyridine (Hbmp) and [Cu(CH3CN)4](ClO4) as the starting materials. As revealed by single-crystal X-ray diffraction, compound 1 is a Cu(I)Fe(II) heterodinuclear complex, in which the Cu(I) ion adopts a four-coordinate mode and connects with two N and two P atoms to form a distorted tetrahedral configuration, while the Fe(II) ion is sandwiched between two cyclopentadienyl moieties to generate a staggered sandwich biscuit geometry. Complex 1 has a weak low-energy broad absorption in the 355~460 nm region, which is assigned to metal-to-ligand charge-transfer (Cu(I)→Hbmp, MLCT) transition, mixed with some ligand-to-ligand charge-transfer (dppf→Hbmp, LLCT) transition. Keywords: copper(I); benzimidazole; diphosphine; heterodinuclear complex; crystal structure 铜(I)配合物因原料价廉丰富、结构配位多样、化学物理性质独特及在有机发光二极管、光伏器件、传感器和生物标记等领域的良好潜在应用而受到各国科学家的广泛关注[1-10]. 1,1′-双(二苯基膦)(dppf)双膦配体由于含有2个强配位能力的磷原子，它能够以螯合和桥联两种配位方式与各种过渡金属离子发生作用，形成结构及配位多样的单核、双核和多核的金属配合物，同时由于它还含有1个镶嵌在两平行环戊二烯基之间并具有良好氧化还原性质的铁(II)离子，因而可被广泛应用于催化、合成和传感器等诸多领域[11-13]．因此，本文选择2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)为氮杂环三齿配体，1,1′-双(二苯基膦)(dppf)为双膦辅助配体，与[Cu(CH3CN)4](ClO4)进行分子组装反应，合成得到了一个铜(I)[Cu(Hbmp)(dppf)](ClO4) (1)，并对其分子结构和光谱性质进行了表征． 1 实验部分 1.1 主要试剂和仪器 ′-双(二苯基膦)(分析纯)购于有限公司2-(2-苯并咪唑基)-6-甲基吡啶和[Cu(CH3CN)4](ClO4)根