流体化床Fenton深度处理合成制药废水研究.docxVIP

流体化床Fenton深度处理合成制药废水研究 摘要：采用流体化床fenton装置深度处理合成制药废水，通过 止交试验确定了处理合成制药废水的最佳条件是hrt为20min,初 始 ph 值为 4.0, h 2o 2/cocl cr 4.0, h 2o 2/fe 2+ 15,且在最佳条件下出水cod cr 稳定在80mg/l以下，可以达到《污水综合排放标准》 (gb8979-1996) 一级标准。同时将其与标准fenton氧化法进行对 比试验，结果显示流体化床fcntoncod cr 13% 以上，污泥产牛量可降低70%,运行成本可减低28%,稳定运行成 本可以控制在3. 0元/吨废水以内。 关键词：流体化床fenton；深度处理；合成制药废水 中图分类号：x703 文献标识码：a文章编号:1007-0370 (2012) 01-0118-04 study on the advanced treatment of synthesis pharmaceutical wastewater by fluidized bed fenton wang fuchao 1, mei rongwu 1, liu jun 2 (1. environmental science research design institute of zhejiang province, hangzhou 310007: 2. school of construction engineering, zhejiang university of technology, hangzhou 310014) abstract： the fluidized-bed fenton reactor was employed for advanced treatment of synthesis pharmaceutical wastewater? through orthogonal tests, the best reaction conditions for synthesis pharmaceutical wastewater t reatme nt were det erm ined as 20 min of hrt, 4. 0 of initial ph value, 4. 0 of h 2o 2/cod cr mass ratio and 15 of h 2o 2/fe 2+ moore ratio. undor those optimum conditions, cod cr concentration of the effluent was detected stably below 80 mg/1, which comp lies with the class a of integrated wastewater discharge standard (gb8978-1996)? comparing to the standard fenton oxidation, the application of fluidized-bed fenton reactor resulted in an improvement of over 13% on cod cr removal efficiency, as well as a reduction of 70% on sludge yield. accordingly, the operating costs can be reduced by 28%, which could be controlled within 3. 0 yuan/tons waste water in stable conditions? key words： fluidized-bed fenton; advaneed treatment; synthesis pharmaceutical wastewater 医药化工废水是一类水质成分复杂、有机污染物浓度高、含有较高 氯化物等无机盐、可纶化性差的工业废水，特别是合成制药废水， 大多含难降解有机物［1］。目前大多数合成制药企业的废水处理都 采用传统的以生化为主体的处理工艺［2］, 一方面废水污染物浓度 高、对微生物系统高效运行影响因素多，处理效率低；另一方面随 着环保要求日益提高，废水处理达标率逐渐下降，许多企业废水排 放难以达标。因此，研究经济适用的合成制药废水深度处理新工艺 势在必行。 流体化床fenton氧化工艺是非均相fenton氧化技术基础上发展而 来的，主要原理是将fenton氧化法产生的三价铁在流化床中的载 体表面产生feooh的结晶［3］,而feooh是h 2o 2的一种