毕业设计-聚合物导电粒子的介电改性研究.docVIP

- PAGE I - 本科毕业设计 （20 届） 聚合物/导电粒子的介电改性研究 所在学院 专业班级 应用物理 学生姓名 学号 指导教师 职称 完成日期 年 月 PAGE I 【摘要】 有机高分子电介质材料因其具有极佳的力学属性而受到广泛关注，但一般聚合物的介电常数普遍偏低，通过添加导电颗粒使复合材料发生渗流效应，利用渗流转变时复合材料的奇异性能可以获得极高的介电常数。本文主要研究了PVDF/Ni、PVDF/Fe3O4等复合体系的介电学性能。研究发现，在PVDF基体中添加Ni、Fe3O4等导电粒子，可以使复合材料发生渗流效应，在Ni颗粒的质量分数为50%时，PVDF/Ni复合材料发生绝缘体-导体相变，介电常数达到65；在体积分数为6.5%的PVDF/Fe3O4复合体系中，介电常数高达100，电导率增加近六个数量级，复合材料发生渗流效应。这两种改性方法都在一定程度上增大了介电损耗，但是其有效值均保持在一个较低的数值范围内。 【关键词】聚合物；导电粒子；介电常数。 Abstract 【ABSTRACT】 Organic polymer dielectric material received extensive attention because of its excellent mechanical properties, but in general the dielectric constant of the polymer is generally low, by adding the conductive particles of the composite percolation occurs, the use of flow changes in the singular properties of the composites can get very high dielectric constant. This paper primarily studies medium electrical properties of composite system such as the PVDF / Ni, PVDF/Fe3O4. Study found that adding the PVDF matrix, Ni, Fe3O4 and other conductive particles, can occur in percolation composites, the Ni particles when the mass fraction is 50%, PVDF / Ni composites occurred insulator - conductor phase transition, dielectric constant to 65; in the PVDF/Fe3O4 composite whose system volume fraction is 6.5%, the dielectric constant up to 100, it will cause nearly six orders of magnitude increase and conductivity of the composite occurrence of percolation. Both methods are modified to increase the dielectric loss to some extent, but the valid values are maintained at a lower value range. 【KEYWORDS】polymer；cnductive particles ；dielectric constant。 目　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc291841715 摘　要 PAGEREF _Toc291841715 \h II HYPERLINK \l _Toc291841716 Abstract PAGEREF _Toc291841716 \h III HYPERLINK \l _Toc291841717 目　录 PAGEREF _Toc291841717 \h IV HYPERLINK \l _Toc291841718 1 绪论 PAGEREF _Toc291841718