毕业设计-无铅压电陶瓷的制备.docVIP

- PAGE I - 本科毕业设计 （20 届） 无铅压电陶瓷的制备 所在学院 专业班级 应用物理 学生姓名 学号 指导教师 职称 完成日期 年 月 PAGE \* MERGEFORMAT II 摘要 【摘要】制备出了性能优良的BNBT并向BNBT中掺入了0.01KNbO3、0.02KNbO3、0.04KNbO3、0.08KNbO3，分析了不同浓度对晶粒的形貌、大小，晶界的影响；并发现浓度为0.01左右的KNbO3对于陶瓷的均匀生长最有利，生成的陶瓷的致密性最好、晶界清晰、晶粒大小均匀；总结了介电异常峰的位置与KNbO3浓度的关系；得到了改变掺杂不同浓度的KNbO3而引起的陶瓷压电性能的变化趋势；分析了不同浓度的KNbO3的电滞回线，并且随着掺入的KNbO3的量越大，其矫顽场强越小，得到了BNBT-xKN在温度Td处发生了宏畴-微畴转变，剧烈的热运动导致在Td以上由宏畴逐渐向微畴转变，从而形成“双电滞回线”。 【关键词】压电陶瓷；无铅；介电；压电；电滞回线  Abstract 【ABSTRACT】BNBT were prepared by ordinary solid-state ceramic processing , and mixed with the 0.01KNbO3, 0.02KNbO3, 0.04KNbO3, 0.08KNbO3, analysis that different concentration effects on crystal size, surface topography and boundary , and find that a concentration of about 0.01 KNbO3 can produce better ceramic with clear boundary, and uniform size; We summaried the relationship of the dielectric anomaly peak position with the concentration of KNbO3; We also got that different concentration of KNbO3 ceramics can change the Piezoelectricity ; We analysis the hysteresis loops of different concentration of KNbO3 , and with the greater amount of doped KNbO3, the smaller the coercive field obtained .In the temperature Td BNBT-xKN occurred the Macro－Micro domain transformation, resulting that intense thermal motion at Td lead the micro-macro domain transformation, thus forming the double-hysteresis loop. 【Keywords】Piezoelectric Ceramics; Lead-free; dielectric constant; Piezoelectric constant; hysteresis loops 目录 TOC \o \u 目录 PAGEREF _Toc292016817 \h IV 1 绪论 PAGEREF _Toc292016818 \h I 1.1 简介 PAGEREF _Toc292016819 \h I 1.2 表征压电材料性能的参数 PAGEREF _Toc292016820 \h II 1.2.1 压电性原理 PAGEREF _Toc292016821 \h II 1.2.2 压电材料的性能表征参数 PAGEREF _Toc292016822 \h IV 1.3 目前压电材料按其组成和形态的分类 PAGEREF _Toc292016823 \h IV 1.3.1 压电单晶 PAGEREF _Toc292016824 \h V 1.3.2 压电陶瓷 PAGEREF _Toc292016825 \h V 1.3.3 压电聚合物 PAGEREF _Toc292016826 \h