毕业论文-杂多酸催化氧化处理印染废水研究.docVIP

杂多酸催化氧化处理印染废水研究 PAGE 16 本科毕业设计 环境工程 杂多酸催化氧化处理印染废水研究 Oxidation of dyeing wastewater catalysed by supported heteropolyacids PAGE 15 摘　要 【摘要】采用活性炭作为载体固载磷钼酸这种非均相催化体系研究了二氧化氯化学氧化体系与二氧化氯催化氧化体系在处理印染废水中的应用，重点研究了活性炭反应塔在二氧化氯作用下连续运行的状况。结果表明磷钼酸固载在活性炭上形成的固载型催化剂催化效果明显，能使酸性大红GR染料废水脱色率和COD去除率提高20%左右；装有固载型催化剂的反应塔可以实现连续循环运行，载体由于氧化剂在其表面的反应而始终保持活性。 【关键词】活性炭；二氧化氯；催化氧化。 Oxidation of printing and dyeing wastewater catalysed by supported heteropolyacids Abstract 【ABSTRACT】The?chlorine dioxide?chemical oxidation?system and?ClO2 catalytic oxidation system were studied and focused on the continuous operation?conditions of activated carbon?reaction column under the?oxidation of?the?chlorine dioxide. Phosphomolybdate was used as a catalyst?and supported by activated carbon?in the experimental system.?The results show that?phosphomolybdate?catalyst supported by activated carbon has obvious Catalytic effects,?improving the?Acid Brilliant Scarlet GR?wasterwater decolorization ratio and the?COD?removal ratio by about 20, the?reaction tower?filled with phosphomolybdate supported by activated carbon can be operated continuously, the activated carbon?remain?active as??oxidant reacting on its surface. 【KEYWORDS】activated carbon；chlorine?dioxide；catalytic oxidation. 目　录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc292997114 摘　要 PAGEREF _Toc292997114 \h II HYPERLINK \l _Toc292997115 Abstract PAGEREF _Toc292997115 \h III HYPERLINK \l _Toc292997116 目　录 PAGEREF _Toc292997116 \h IV HYPERLINK \l _Toc292997117 1 引言 PAGEREF _Toc292997117 \h 1 HYPERLINK \l _Toc292997118 2 理论部分 PAGEREF _Toc292997118 \h 2 HYPERLINK \l _Toc292997119 2.1 杂多酸的催化作用 PAGEREF _Toc292997119 \h 2 HYPERLINK \l _Toc292997120 2.2 活性炭的结构与性能 PAGEREF _Toc292997120 \h 2 HYPERLINK \l _Toc292997121 2.2.1 活性炭的结构 PAGEREF _Toc292997121 \h 2 HYPERLINK \l _Toc292997122 2.2.2 活性炭的性能 PAGEREF _Toc292997122 \h 3 HYPERLINK \l _Toc292997123 2.3 活性炭负载杂多酸非均相催化剂的形成机理 PAGEREF _Toc292997123 \h 4 HYPERLINK \l _Toc292997124 2.4 二氧化氯的理化性质 PAGEREF _Toc