含PANI嵌段和PEG嵌段共聚物自组装的结构调控-高分子化学与物理专业论文.docxVIP

I I 摘 要 以具有明确化学结构的(PANI)98-(PEG)136-(PANI)98 三嵌段共聚物为研究对象，通 过 选 择 合 适 的 溶 剂 、 溶 液 浓 度 、 外 界 条 件 以 及 样 品 的 制 备 方 式 ， 实 现 了 (PANI)98-(PEG)136-(PANI)98 自组装的结构调控。研究结果表明：在相同的溶液浓度下， (PANI)98-(PEG)136-(PANI)98 在 NMP、DMF、无水乙醇和水中分别自组装成球形、棒状、 网状以及纤维带状结构。(PANI)98-(PEG)136-(PANI)98 在无水乙醇中，随着浓度的增加， 自组装形成的网状结构由单层转变为多层、立体网状和花瓣状结构；在 DMF 中， (PANI)98-(PEG)136-(PANI)98 受浓度影响，可自组装形成棒状、管状和“实心洋葱”等 核-壳结构；在 NMP 中，则可自组装形成球形和棒状结构。金属盐（LiCl）的加入能 使(PANI)98-(PEG)136-(PANI)98 自组装形成的纤维带状结构变长；而超声波作用则使 (PANI)98-(PEG)136-(PANI)98 自组装结构明显地细化。自组装样品的制备方式对其自组 装行为也有明显的影响。 此外，通过分子设 计，用碳纳米管代 替聚苯胺作为刚性 链段合成了 MWNT-PEG-PANI，研究了它在溶剂中的自组装行为。结果表明，MWNT-PEG-PANI 在 NMP 中自组装形成了以 MWNT 为核、聚合物为壳的刚性棒状结构。 关键词：嵌段共聚物， 自组装， 结构调控， 碳纳米管 II II Abstract The self-assembly behaviors of (PANI)98-(PEG)136-(PANI)98 block copolymer with defined-chemical structure were investigated in different selective solvents, such as NMP, DMF, ethanol and water. The influences of selective solvents, solution concentrations, additional factors and preparation methods of samples on self-assembly were discussed. At the same solution concentration, the block copolymer can form particles, rods, fiber networks and fiber bands in the above solvents, respectively. Especially, with increasing the solution concentration in ethanol, the block copolymer can form multi-layer, tri-dimensional fibrous network, and petaline structure from the mono-layer fibrous network. In DMF, (PANI)98-(PEG)136-(PANI)98 solutions can form rods, solid onions, and tubes with the increasing their concentration. And the self-assembly structures of (PANI)98-(PEG)136-(PANI)98 are changed from small particles to long rods with increasing the solution concentration in NMP. Addition of Li+ to its solution in water induces an increase in the length of fiber band as compared to the starting solution. Also, the ultrasonic and preparation method of samples have an obvious effect on self-assembly behaviors of the block copolymer. Moreover, MWNT-PEG-PANI copolymer was synthesized using mu