含荧光基团低聚物的合成及在水处理中的应用-应用化学专业论文.docxVIP

博士论文 博士论文 吉荧光基团低聚物的合成及在水处理中的应用 Abstract Two kinds of water soluble fluorescent monomers，4-methoxy-N-(2-N’N’- dimethylamino ethyl)naphthalimide anyl chloddc quaternary ammonium salt(FhD and ■ aUyl chloride quaternary salt of 4-methoxy-N-(3-N；N-dimethylaminopropyl) naphthalimide(4一MNDMAPN-AQ)，were synthesized．The structure of the products was characterized by R 1H NMlL MS and elementary analysis．The optimum reaction conditions were obtained by experiments． FM—MA-A气4-MNDMAPN-AQ-AM-A～ F-PAM were prepared by copolymerization offluorescence monomers with maleic anbydride(MA),acrylic acid(AA) and∽r)，l锄ide(舢田，respectively．The copolymerization rule was studied and the optimized conditions wate obtained． The fluorescent spectra ofthe copolymers were investigated．The results showed that the excited and the emitted wavelength of the eopolymers containing fluorescent monomer were the same as those of the monomers respectively．The fluorescent performance of the copolymers was evaluated．The effects of pH,the change of concentration of NaCIO and ■ 1227 and the sunshine time on the fluorescent intensity were surveyed．The results showed： The fluorescence intensity of the polymer ffM-Ma一心Was constant at pH=5,一8 and the fluorescent intensity of polymer(4-MNDMAPN-AQ·AM-AA)was constant at p}p7~10． The general used inhibitors had no influences on the fluorescent intensity,and to some extent,the oxidants and sumkine time would cau5e the fluorescent intensity weak．The calibration curve for the determination of 4-·MNDMAPN--AQ-AM-AA Was linear over the range from 1 mg·L．1 to 10 mg·L．1，with the detection limit for 4-MNDMAPN-AQ—AM-AA of 0．5 mg．L-I．The fluorescence intensities also accorded well with the concentration of FM-MA-AAwiththelowlimitof0．64mg·UI overitslinearrange． By means of bubble,precipitation and pH shill the performance of scale inhibition was researched,and the results w