含纳米碳酸钙的镁钙耐火材料性能研究及其对钢水质量的影响-材料科学与工程专业论文.docxVIP

AbstractFree Abstract Free CaO is expected to exist in working lining of tundish for clean steelmaking， which Can purify the steel liquid．Limestone，particle size of which is comlnorlly bellow 0．5mm，was used as the CaO resource during refractories manufacturing process that used for tundish．However，due to the effects of thickness and stmcture of working lining of tundish on heat transfer and decomposition kinetics of limestone， limestone in refractories do not thoroughly decompose in preheating．C02 gas from decomposition of the residual limestone would enter in molten steel，and then have effects on steel quality in continuous casting via the reactions between C02 and elements in steel．Larger pores are produced from decomposition of limestone，which would reduce strength of materials also． Nano-CaC03 was used instead of limestone as CaO resource in MgO-CaO refractories fabrication in this study，MgO—CaO dry vibration material and MgO-CaO castable were fabricated and effects of nano-CaC03 content on properties of materials were studied．Mixes Was also made in crucible shape．Effect of MgO-CaO crucible containing llano-CaC03 reacting with molten steel on Mn，C content and total oxygen content in steel were investigated via induction furnace．The conclusion are shown as followed： 1 1 Nano-CaC03 could fiU pores when it is introduced in dry vibration material．The pore size distribution of specimens heated at 1 500。C transfer to unidomal distribution from the bimodal distribution，and average pore diameter is decreased，apparent porosity is increased．Apparent density and strength of dry vibration material were better when addition content of nano·CaC03 is 2．5wt％．The strength of dry vibration material is increased with the increment of phenolic resin content，but pores from decomposition of phenolic resin have a little restriction on sintering．The suitable content of phenolic resin is 1．5bwt％in this experiment． 2)When nano-CaC03 was used in castable，pore size distribution of spec