含氟环铂(Ⅱ)配合物的合成及其发光氧传感性能-应用化学专业论文.docx

含氟环铂(II)配合物的合成及其发光氧传感性能(∞研究了EC膜的厚度对发光氧传感响应时间及恢复时间的影响规律。结果表明， 含氟环铂(II)配合物的合成及其发光氧传感性能 (∞研究了EC膜的厚度对发光氧传感响应时间及恢复时间的影响规律。结果表明， 以快速响应为目标，EC膜的最佳膜厚为5．88岬。在最佳膜厚下，LXB3氧传感膜得到 相同的响应时间与恢复时间，均为2．7 S。LXBl一LXB3及Pt(ppy)(acac)@，LXBl具有 最高的氧敏感性，THF中LXBl的而偈61为14．0，碟害p为182．2 barl；Ec膜中LXBl 的lo／1100为8．5，船p为16．1 bar1。 (5)研究了取代基对环铂(II)配合物碰撞半径(力的影响规律及含三苯胺基环铂(II)ff己 合物LSYCl-LSYC4的氧传感性能。结果表明，基于Pt(ppy)(acac)，在环金属配体的苯 环4位引入4-(--苯氨基)苯基对环铂(II)配合物碰撞半径的影响不明显：在吡啶环5位引 入三氟甲基(．CF3)、氟原子或延长共轭结构会缩小碰撞半径，而引入甲基(一CH3)对碰撞半 径影响不明显；在苯环3位或4位引入苯基或氟代苯基可增大碰撞半径。LSYC卜LSYC4 Pt(ppy)(acac) ，LSYCl具有最高的氧敏感性，THF中LSYCl的而偈61为140．8，F叩Vp为 1948．2 barl，对氧气的检测限达0．0344 mbar；EC膜中LSYCl的而仉00为19．9，ⅣaVpp为 39．9 bar-I。 关键词：发光氧传感；环铂(II)配合物；氟；光稳定性；响应时间 万方数据 大连理工大学博士学位论文ABSTRACT 大连理工大学博士学位论文 ABSTRACT Optical oxygen sensors have wide applications in fields of biomedicine，food technology and environment because of overwhelming features，such as no oxygen consumption during measurements，full reversibility and good precision and accuracy．Optical oxygen sensors are based on the dynamic quenching process of phosphorescence(or delay fluorescence)of oxygen‘sensitive probes(OSPs)by molecular oxygen．In order to rationally construct optical oxygen sensors with excellent oxygen sensing performance，it is necessary to well understand the structure。property relationship(including photophysical property，electrochemical property， photostability，oxygen sensitivity and reversibility)of the OSPs．Although Pt(1I)porphyrins have often been reported as OSPs in the field of optical oxygen sensing，cyclometalated Pt(II) complexes are alternative OSPs because of their strong room-temperature phosphorescence with high quantum yields and specially long triplet lifetimes． Based on the Pt(ppy)(acac)，eighteen novel cyclometalated Pt(II)complexes with trifluoromethyl(-CF3)，fluorophenyl，phenyl，4-(diphenylamino)phenyl substituents and fluorine atoms were designed and synthesized，respectively．These complexes were further used as OSPs to study their photophysical，electroch