含铝铁硅固废制备PSAF混凝剂RSM优化与结构表征.PDFVIP

中国环境科学 2018,38(10) ：3720~3728 China Environmental Science 含铝铁硅固废制备 PSAF 混凝剂 RSM 优化与结构表征 劳德平 1,丁书强 2*,倪 文 1,许成文 1,李晓光 2,马 宁 2 (1.北京科技大学土木与资源工程学院,北京 100083 ；2.北京低 碳清洁能源研究院,北京 102211) 摘要：研究了以粉煤灰和氧化铁皮为原料制备聚硅酸铝铁混凝剂的影响因素及产品微观结构和形貌,选取碱化度、nAl:nFe 、聚合温度、反应时间对透 光率进行 4 因素 3 水平响应面实验.得出制备优化方案:碱化度为 0.5, nAl:nFe 为 1.38,聚合温度为 39.2℃,反应时间为 1.36h,透光率预测值达 90.24%,验 证试验均值相对误差 1.20%,表明 RSM 优化模型可靠.结合产品表征测试,XRD 分析主要物相为氯化钠,大范围衍射驼峰预示着浸出液聚合形成了新的 无定形物;FT-IR 测试表明聚硅酸与 Al3+ 、Fe3+之间存在较多金属-OH 等非离子键络合态;TEM 测试结果显示产品为高聚集度和枝化度的网状结构;TG 分析表明产品在 400 ℃以前失去结合水和羟基,700℃左右产品主要化学键断裂,对应 DSC 图中均出现较强吸热峰,产品具有较好的稳定性. 关键词：粉煤灰；氧化铁皮；聚硅酸铝铁(PSAF) ；响应面(RSM) ；透光率 中图分类号：X752 文献标识码：A 文章编号：1000-6923(2018)10-3720-09 Preparation polysilicate aluminum ferric coagulant from solid waste which containing aluminum, iron and silicon: response surface method optimization and microstructure characterization. LAO De-ping1 2∗ 1 1 , DING Shu-qiang , NI Wen , XU Cheng-wen , 2 2 LI Xiao-guang , MA Ning (1.School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China；2.National Institute of Clean and Low Carbon Energy, Beijing 102211, China). China Environmental Science, 2018,38(10) ：3720~3728 Abstract ：This paper investigates the factors that influence the preparation of polysilicate aluminum ferric coagulant using solid wastes which containing and their microstructure and morphology. Four factors (basicity, nAl: nFe, polymerization temperature and reaction time) and three levels of response surface experiments were carried out, which regarded the transmittance as the evaluation index. Results showed that the optimum scheme when the basicity was 0.5, the nAl: nFe was 1.38, the polymeri