淀粉接枝改性引发方式及聚合方法.PDFVIP

Hua Xue Fa Zhan Qian Yan Scientific Journal of Frontier Chemical Development 淀粉接枝改性引发方式及聚合方法* 贺小贤，刘苗苗，孙福林，赵会芳 陕西科技大学 生命科学与工程学院，陕西 西安 710021 摘 要：淀粉接枝共聚物是一类新型功能性生物材料，具有天然高分子材料和合成高分子材料的双重性能，近年来得到了研究者 的广泛重视。本文综述了淀粉接枝共聚改性方法的研究进展，着重介绍了光引发、Co60 射线引发、微波辐射引发、硝酸铈铵引发、 氧化还原引发等链引发方式以及水溶液聚合、反相乳液聚合等聚合方法,为淀粉接枝共聚过程中引发剂和聚合方法的选取提供一 些参考，并对其存在的问题和发展的方向进行了展望，指出接枝改性淀粉的研究重点，为人们进一步认识和研究淀粉接枝共聚物 提供思路。 关键词：淀粉；接枝共聚物；改性；引发方式；聚合方法 Initiation and Polymerization of Starch Graft Modification ﹡ Xiaoxian He , Miaomiao Liu, Fulin Sun, Huifang Zhao College of Life Science and Engineering, Shaanxi University of Science and Technology, Xi’an, China, 710021 Email: hexx@ Abstract: As a new type of functional biological material, the graft copolymer of starch possesses properties of both natural polymers and synthesis ones, which has got extensive attentions in recent y ears. Latest advances in the initiation methods of starch graft copolymerization are introduced in this paper, mainly focusing on several initiation methods, such as photo-initiation, Co60 γ-ray initiation, microwave initiation, ceric ammonium nitrate initiation, and redox initiation. Besides, different polymerization methods are present, such as water-solution polymerization, inverse-emulsion polymerization, etc. We expect this paper could make some contributions for researchers to choose proper initiation and polymerization methods in the process. In addition, it is also discussed in this paper of the problems and developmental directions, pointing out the research emphases of starch grafting modification and providing new thoughts for further study. Key words: Starch; Graft Copolymer; Modificatio