电子烟用金属件中重金属的迁移-烟草科技.PDF

2019 年2 月 烟草科技 Feb. 2019 第52 卷第2 期 Tobacco Science Technology Vol. 52 No.2 电子烟用金属件中重金属的迁移 * 樊美娟，王洪波，赵 乐，崔华鹏，陈 黎，潘立宁，郭军伟，刘惠民 中国烟草总公司郑州烟草研究院，郑州高新技术产业开发区枫杨街2 号 450001 摘要：为评估电子烟用金属件中重金属的迁移风险，依据金属件在储存和工作状态下与烟液、气溶胶及 口腔接触的实际情况，开发了各金属件的迁移实验方法，确定了模拟物种类、模拟物体积、迁移时间和迁 移温度。同时建立了气溶胶体系，丙二醇、丙三醇、烟碱和水的混合物体系，以及水体系中镍、铬、铅、砷 和镉的电感耦合等离子体质谱（ICP-MS ）分析方法，并对30 个电子烟样品金属件中重金属的迁移量进 行测定，同时对其来源进行分析。结果表明：①加热丝中的镍存在向气溶胶迁移的风险，迁移量为0.02~ 0.93 μg/200 口；②与烟液/ 气溶胶接触的金属件存在铅迁移的风险，迁移量为0.01~ 1.30 mg/kg ，主要源于 铜锌合金中杂质铅的迁移；③与口腔接触的金属件不存在重金属迁移的风险。 关键词：电子烟；金属件；重金属；金属迁移；迁移风险 中图分类号：TS411.2 文献标志码：A 文章编号：1002-0861 （2019 ）02-0040-07 Migration of heavy metals from metal assemblies in electronic cigarettes * FAN Meijuan, WANG Hongbo, ZHAO Le , CUI Huapeng, CHEN Li, PAN Lining, GUO Junwei, LIU Huimin Zhengzhou Tobacco Research Institute of CNTC, Zhengzhou 450001, China Abstract ：In order to assess the migration risk of heavy metals in metal assemblies of electronic cigarettes, a migration test method for identifying heavy metals was developed according to the actual conditions of metal assemblies ’contacting with e-liquid, aerosol and mouth under storage and working conditions. The type and amount of simulant, the time and temperature of migration were determined. An ICP-MS (Inductively Coupled Plasma Mass Spectrometry) analysis method was developed for identifying nickel, chromium, lead, arsenic and cadmium as potential migrants in the following three simulants: a) aerosols; b) the mixture of propylene glycol, glycerol, nicotine and water; c) water. The migration amounts of heavy metals from metal assemblies in 30 e-cigarette sample