环氧氯丙烷改性花生壳对次甲基蓝的吸附研究-生物质化学工程.PDF

第42卷第2期 生摇 物摇 质摇 化摇 学摇 工摇 程 Vol.42 No.2 2008年3月 Biomass Chemical Engineering Mar. 2008 环氧氯丙烷改性花生壳对次甲基蓝的吸附研究 1,2 1 2* 李 山 ,张丽娜 ,樊君 (1.长安大学环境科学与工程学院, 陕西 西安 710054;2. 西北大学化工学院, 陕西 西安 710069) 摘摇 要:以花生壳为原料,环氧氯丙烷为改性剂,对花生壳进行改性制备吸附剂,并对其吸附次甲基蓝的性能作了较系统 的研究。 结果表明,在2.0g花生壳中分别加入1.25mol/ L的NaOH溶液45mL和环氧氯丙烷25mL,控制温度40 益,搅 拌反应30min,经过滤、水洗干燥后得到改性的花生壳,用此改性的花生壳吸附次甲基蓝的最佳条件为:处理100mg/ L 的次甲基蓝溶液50mL,用0.2g改性花生壳,pH值在6.48,搅拌吸附60min,在此条件下吸附率可达99%,吸附后的花 生壳用0.5mol/ LNaOH溶液再生,重复使用3 次对次甲基蓝的吸附率在96% 以上;未改性花生壳对次甲基蓝的吸附率 仅为82%。 关键词:环氧氯丙烷;花生壳;次甲基蓝;吸附 中图分类号:TQ91;TQ424摇 摇 摇 摇 摇 摇 摇 文献标识码:A摇 摇 摇 摇 摇 摇 摇 文章编号:1673-5854(2008)02-0030-03 Study on Adsorption of Methylene Blue in Solution with Epichlorohydrin Modified Peanut Shell 1,2 1 2 LI Shan ,ZHANG Li鄄na ,FANJun (1.College of Environmental Science and Engineering,Chang忆an University,Xi忆an710054,China; 2.College of Chemical Engineering,Northwest University,Xi忆an710069,China) Abstract:An absorbent was preparedfrom peanut shell by epichlorohydrin modification. Its adsorption performance for methy鄄 lene blue in solution was also studied. The results indicate:the modified peanut shell was obtained by using 1.25mol/ L NaOH solution45mL and epichlorohydrin25mL to modify2.0g peanuts shell,controlling reaction temperature at40 益,mixing time for 30min,filtering,waterwashinganddrying. Theoptimaladsorptionconditionofmodifiedpeanutshelltomethylenebluewas: 50mL of 100mg/ Lmethyleneblue solution,0.2g modifiedpeanut shell,pHvalue6.48,stirringtime 60min. The adsorption rate of modified peanut shell was99%. The used peanut shell could be regenerated by0.5mol/ L