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42 1 () Vol.42 No.1
2011 1 Journal of Central South University (Science and Technology) Jan. 2011
β-
( 413000)
10%Pd/C
β-Pd/C
Pd/C
β--β--β-β-10% Pd/C 100׃5β-
1׃350 mL150 W50 8 minβ-
100%-β-94.8%Pd/C 6
β--β-
O622.4 A 1672−7207(2011)01−0033−05
Selective reduction of β-ionone during ultrasounic irridiation
LIU Chang-hui, LONG Li-ping, HOU Xiao-bin
(Department of Chemistry and Environmental Engineering, Hunan City University, Yiyang 413000, China)
Abstract: The procedure of selective reduction of β-ionone by ammoniumformate as hydrogen donor and mass fraction
10% of Pd/C as catalyst was studied using anhydrous ethylol as solvent during the ultrasonic irridiation. The effect of
ultrasonic power, reaction temperature, reaction time, the quantity of 10% Pd/C and ammoniumformate were investigated,
and the reaction conditions were optimized, and the products were characterized by IR, 1H-NMR, 13C-NMR, MS and
elemental analysis. The results show that conversion of β-ionone 100% and dihydro-β-ionone is the major product in
yield of 94.8% along with dihydro-β-ionol under the conditions as follows: m(β-ionone)׃ m(10%Pd/C) is 100׃5,
n(β-ionone) ׃n(HCOONH4) is 1׃3, ultrasonic power 150 W and anhydrous ethylol 50 mL at 50 for 8 min at ambient
pressure. The Pd/C catalyst is easy for recovery and can be reused again over 6 times.
Key words: β-ionone; ultrasonic irradiation; catalytic reduction; ammoniumformate; dihydro-β-ionone
-β- (2)
β-
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