邻菲罗啉光度法测定纳米二氧化钛中铁含量-钢铁钒钛.PDF

27 1 Vol. 27, No. 1 2006 3 IRON STEEL VANADIUM TITANIUM Marc 2006 郑小敏, 汪雪梅, 杨 平 ( , 617000 ) : TiO , , pH 5. 5 2 ) , , 510 nm , 4 E= 4. 7@ 10 , 100 mL , 0~ 100 Lg , , 4% , 94. 95% ~ 105. 33% : ; ; : O652 :A : 1004- 7638(2006) 01- 0064- 04 Determination of Iron in Nano- TiO by 1, 10- phenanthrolin 2 Spectrophotometry Z eng Xiaomin, Wang Xuemei, Yang Ping ( Panz i ua Iron Steel Researc Institute, Panz i ua 617000, Sic uan, C ina) Abstract:A determination met od of iron content in nano- T iO w as presented, in w ic t e sample 2 was dissolved into sulfuric acid and ammonium sulfate, t e titania ion w as masked by ammonium tar- 2+ trate. T e 1, 10- p enant rolin reacted w it Fe to form a stable orange- red complex in t e med-i um of CH COOH ) CH COONa( pH 5. 5) . T e absorbance w as measured at t e w avelengt of 510 3 3 4 nm. T e apparent molar absorptivity is 4. 7 @ 10 and it is obeyed Beer law in t e range of 0~ 100 Lg/ 100 mL for iron concentration. T e proposed met od is of very good selectivity for determining iron in nanometer titania samples, t e relative standard deviation is below 4% , and t e recovery is in t e range of 94. 95% ~ 105. 33%. Key wor s: nanometer titania; iron;