通过试验教学探讨配位化学基本概念.pdf

大学化学(Daxue Huaxue) 68 Univ. Chem. 2016, 31 (5), 68－72 May ∙师生笔谈∙ doi: 10.3866/PKU.DXHX201506003 通过实验教学探讨配位化学基本概念 陈水生* 盛良全 乔 瑞 杨 松 (阜阳师范学院化学与材料工程学院，安徽阜阳236041) II I 摘要：以4-咪唑基苯甲酸(H L)为配体，与硝酸铜反应合成铜的配合物[Cu Cu (HL)(L)(H O) ] ∙H O 。通过 2 2 2 2 配合物的合成、结构表征、结构分析的实验教学过程，引导学生挖掘并理解配位化学学科的基本概念及 理论，培养学生将理论与实践相互结合的能力，促进学生自身知识体系的构建。 关键词：配位化学；实验教学；理论知识体系 中图分类号：O611.4 ；G642 Exploration on the Basic Concept of Coordination Chemistry via Laboratory Teaching CHEN Shui-Sheng* SHENG Liang-Quan QIAO Rui YANG Song (College of Chemistry Chemical Engineering, Fuyang Normal College, Fuyang 236041, Anhui Province, P. R. China) II I Abstract: The synthesis of a copper complex [Cu Cu (HL)(L)(H O) ] ∙H O based on the hydrothermal 2 2 2 synthesis of 4-(1H-imidazol-4-yl)benzoic acid (H L) with Cu(II) cation, was taken as laboratory teaching 2 project for undergraduates, which covered the aspects of the designed synthesis, structural characterization and analysis. The aim of the laboratory teaching is to enhance the theoretical knowledge of coordination chemistry, promote th