发射光谱法测定区域地质调查样品中锡元素不确定度评定.pdfVIP

45 卷 9 期 当 代 化 工 Vol.45，No.9 2016 年9 月 Contemporary Chemical Industry September，2016 射光谱法测定区域地质调查样品中 锡元素不确定度评定 马 龙，霍成玉，胡兰基 （青海省地质矿产测试应用中心，青海西宁 810008 ） 摘 要：根据测量不确定度评定与表示理论，采用一米光栅发射光谱法测定区域地质调查样品锡元素的不 确定度评定，分析了该方法在测试区域地质调查样品银的不确定度主要来源，确立了数学模型，并对各不确定 度分量进行评定、计算合成不确定度、扩展不确定度。评定方法适用于评定测量区域地质调查样品中锡的不确 定度，其方法简便，置信度范围内 95% ）结果准确、可靠。该不确定度评定方法在实际工作中具有较强的实 用价值。 关 键 词：发射光谱法；区域地质调查样品；锡；不确定度；评定 中图分类号：O 657 文献标识码： A 文章编号： 167 1-0460 20 16 ）09-2270-03 Evaluation of Uncertainty in Determination of Tin in Geochemical Samples by Emission Spectrometry MA Long, H UO Cheng-yu , HU Lan-ji (Qinghai provincial geological and mineral testing and Application Center, Qinghai Xining 810008, China Abstract: According to the measurement uncertainty evaluation and representation theory, the uncertainty in determination of tin in geochemical samples by emission spectrometry was evaluated, main sources of the uncertainty were analyzed, the mathematical model was established, and different uncertainty components were evaluated, synthetic uncertainty and expanded uncertainty were calculated. The assessment method is suitable for measuring the uncertainty in determination of tin in the regional geological samples, the method is simple. In the confidence level range (95%), the results are accurate and reliable. The uncertainty evaluation method has strong practical value in the practical work. Key words: emission spectrometry; geochemical samples; tin; uncertainty; evaluation 测量不确定度表征合理地赋予被测量之值的分 合物作缓冲剂，与试样1:1 研磨 合，装入两根同样 散性，与测量结果相联系的参数，是测量结果质量的 规格石墨电极中，滴加凝固剂 2%蔗糖乙醇水溶液）， 定量表征，是对检测过程中影响试验数据的主要因素 以平头石墨电极为上电极