光固化快速成型材料的研究与应用-机械制造及其自动化专业论文.docxVIP

光固化快速成型材料的研究与应用摘要 光固化快速成型材料的研究与应用 摘要 光固化快速成型工艺的核心问题之一是成型材料一光敏树脂的开发。本论文对该 工艺目前使用的紫外光敏树脂进行了改性研究，并在此基础上开发了新型可见光敏 树脂。 在紫外光敏树脂部分，研究了光敏树脂的固化机理、光源与树脂的匹配性，深入 分析了影响树脂性能的因素。实验合成了性能良好的环氧丙烯酸酯预聚物，选择并 复配了与紫外光源匹配的光引发剂，得到了符合光固化快速成型工艺要求的光敏树 脂。 针对研制的紫外光敏树脂固化体积收缩率大的问题，利用螺环膨胀单体在固化时 体积产生膨胀的特性对树脂进行了改性。实验结果表明，添加15％的螺环原碳酸酯 I，5，7，1卜四氧杂螺[5，5]十一烷可以使树脂固化体积收缩率从4．5％降低至1．3％，且 树脂具有较好的综合性能。 在可见光敏树脂部分，通过对咕吨染料碘销盐和菁染料一硼盐体系的吸收光谱性 质、激发态性质、溶剂极性效应、荧光光谱、荧光猝灭、浓度效应、光褪色反应、 光聚合动力学等的研究，结果发现：荧光黄双二苯基碘销盐体系和含喹啉环端基不 对称三甲川菁染料一三苯基丁基硼盐体系在可见光作用下均发生离子对内电子转移 反应，且光褪色反应速率很高。进一步以这两种引发体系作为引发剂，开发出吸收 波长分别为51inm和680nm的两种新型可见光敏树脂。 关键词：光固化快速成型，光敏树脂，膨胀单体，可见光敏引发体系，光褪色反应 博士学位论文 博士学位论文 光固化快速成型材料的研究与应用 Abstract The study of photosensitive resin is a key procedure in Stereolithograghy(SL)．The properties of Ultraviolet(UV)photosensitive resin which are used in SL at present were modified，and new visible photosensitive resins were exploited on the basis of UV photosensitive resin． In the field of UV photosensitive resin，the mechanism of curing，the matching degree of resin-illuminant and the factors affecting the performance of resin were studied in detail．The epoxy acrylate with excellent properties was synthesized，and the resin fit for SL was brought out by using the prepared prepolymer as well as the synergistic initiators which are sensitive tO UV light． In view of the high rate of volumetric shrinkage，UV photosensitive resin was modified by adding spiro orthocabonate 1,5，7，11-tetraoxasplro[5，5]undecane which is expandable，the results show that the rate of volumetric stlIrinkage of the resin decreases by 3．2％to 1．3％with adding 1 5％spiro orthoeabonate and the intergrated properti esof the resin ale still good． In the field of visible photosensitive resin，the absorption spectrum，excited state，solvent polarity effect，fluorescence spectrum，fluorescence quenching，concentration effect，photo fading，reaction mechanism as well as photopolymerization kinetics of xanthene iodonium salts and cyani