武培怡复旦大学高分子科学系.PDF

2008年中国科大 Two-Dimensional (2D) Correlation Spectroscopy 武培怡 复旦大学高分子科学系 1 2008-12-7 Two-Dimensional (2D) Spectroscopy 2 2008-12-7 Generalized 2D Correlation Spectroscopy Generally applicable to a broad range of spectroscopic techniques Based on a set of spectral data from a system under some perturbation Either time-dependent or static spectra may be used Enhance spectral resolution by spreading peaks along the second dimension Selective development of 2D peaks provides better access to information not readily observable in conventional 1D spectra Sign of cross peaks to determine relative direction of intensity changes and sequential order of events Comparison of different spectral data via hetero-correlation 3 Generalized 2D Correlation Spectroscopy Perturbation-based 2D correlation spectroscopy I. Noda, Appl. Spectrosc., 47, 1329 (1993). 4 Reference Literature Applied Spectroscopy , vol. 54, no. 7, July, Y. Ozaki and I. Noda, Eds. Two-Dimensional 2000. (Special issue on generalized 2D Correlation Spectroscopy, AIP Conference correlation spectroscopy) proceedings 503, AIP: Melville, 2000. 5 Book 6 Generalized Two-Dimensional Correlation Spectroscopy Electromagnetic Probe Chemical System Dynamic Spectra IR, NIR, laser …… External Perturbation Temperature,