毕业论文-铜基有机-无机杂化钙钛矿晶体的性能表征与调控.docVIP

PAGE 本科毕业论文 （20 届） 铜基有机-无机杂化钙钛矿晶体的性能表征与调控 专业：高分子材料与工程 摘 要：层状钙钛矿结构有机-无机杂化光电功能材料将有机和无机半导体材料的优点结合在一个分子复合物内，成为当今光电功能复合材料研究的热点之一。 为了研究分子结构对钙钛矿材料的稳定性，我们制备了含直链烷基胺杂化钙钛矿结构材料C4H9NH3Cl和C8H17NH3Cl，以及1,6-己二胺杂化钙钛矿结构材料C12H25NH3Cl，并制备了晶体的薄膜。 为了对杂化钙钛矿层状结构材料进行调控，本文系统研究了直链烷基胺杂化钙钛矿晶体薄膜的后处理，包括温度高低和时间长短对杂化钙钛矿结构材料的结构及性能的影响，红外光谱和紫外-可见吸收光谱分析发现随着温度增高或时间增加对含直链烷基胺杂化钙钛矿系列材料(C4nH8n+1NH3)2CuCl4(n=1,2)的层状结构没有造成破坏，但非对称键的电荷分布发生变化。 关键词：钙钛矿层状结构；有机无机杂化；稳定性；调控；后处理 Characterization and Regulation of the Copper-based Organic - Inorganic Hybrid Perovskite Crystals Abstract: The organic - inorganic materials of the layered perovskite structure combine the advantages of both the organic semiconductor material and the inorganic material in one element, and they have potential applications in the field of photo electrics. In order to research the stability of hybrid perovskite materials, we prepared hybrid perovskite materials C4H9NH3Cl and C8H17NH3Cl including straight-chain alkyl amines and 1, 6-diamane of the hybrid perovskite materials C12H25NH3Cl, and fabricated films of these crystals. In order to regulate and control the properties of layered hybrid perovskite materials, the influence of post-treatment of the aliphatic alkyl amines perovskite crystal thin film was investigated, including the effects of temperature and time on structure and properties of hybrid perovskite materials. The analysis of infra-red spectrum（IR）and the ultraviolet(UV)-Visible absorption spectra indicated that the layered structure of series of the hybrid materials (C4nH8n+1NH3)2CuCl4(n=1,2) containing aliphatic alkyl amine was not damaged when time or temperature of post-treatment increased, but the charge distribution of asymmetric bonds will change. Keywords: layered perovskite structure；organic-inorganic hybrid； thermostability； post- treatment PAGE 1 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc290990524 1 文献综述 1 HYPERLINK \l _Toc290990525 1.1 有机无机复合钙钛矿材料 1 HYPERLINK \l _Toc290990526 1.2 晶体的制备 2 HYPERLINK \l