湿法消解-石墨炉原子吸收光谱法测定大米中的镉.pdfVIP

2015 年第 28 卷第 10 期 粮食与油脂 59 湿法消解-石墨炉原子吸收光谱法测定大米中的镉 傅亚平，吴卫国 （湖南农业大学食品科学技术学院，　湖南长沙　410128 ） 摘　要：该研究采用湿法消解―石墨炉原子吸收光谱法测定大米中的镉含量，选择了最佳的样品 消解剂为硝酸―高氯酸（6 ∶1 ），并确定最佳的测定条件为灰化温度550 ℃、原子化温度1 800 ℃、 基体改进剂为磷酸二氢铵（20 g/L，自动加样2 μL ）。得到的线性回归方程为：Abs 0.059 231Conc+0.004 671 6 ，相关系数r 0.999 9 ，方法检出限为0.3 μg/kg ，精密度（RSD ）为2.55%。 该方法不仅能快速有效地测定大米中的镉含量，还具有操作简单、成本低、回收率高、测定结果准 确可靠等特点。 关键词：大米；镉；石墨炉原子吸收光谱法；湿法消解 Detection of cadmium in rice by wet digestion-graphite furnace atomic absorption spectrometry FU Ya-ping ，WU Wei-guo （College of Food Science and Technology ，Hunan Agricultural University ，Changsha 410128 ，Hunan ，China ） Abstract ：The study aimed to detect cadmium in rice by using GFAAS with wet digestion . The digestion and detection conditions were selected and optimized. When the optimal detection conditions were obtained as follows ：carbonization temperature of 550 ℃，atomization temperature of 1 800 ℃， matrix modifier for NH H PO （20 g/L，automatic sample 2 μL ），HNO –HClO （6 ∶1 ） was taken as 4 2 4 3 4 the optimum digestion liquid for digesting rice samples. The results showed that the regression equation was Abs 0.059 231Conc+0.004 671 6 ，and the correlation coefficient was 0.999 9. The detection limit and RSD of this method were 0.3 μg/kg and 2.55%，respectively. Thus ，this method not only was a rapid and effective detection technology of cadmium in rice ，but also was characterized by simple operation ，low cost ，high recovery ，accurate and reliable results. Key words ： rice ；cadmium ；graphite furnace atomic absorption spectrometry （GFAAS ）；wet digestion 中图分类号：TS210.7 文献标识码：A 文章编号：1008―9578（2015）10―0059―04 大米作为全