光电化学电池TiO,2基电极材料性能的实验研究-热能工程专业论文.docxVIP

摘要氢能被广泛认为是未来擞理想的洁净能源。太阳能分解水制氢被认为魁一 摘要 氢能被广泛认为是未来擞理想的洁净能源。太阳能分解水制氢被认为魁一 种箍具有前景的制氢方法。光电化学电池具有无翻产物、对环境安全、结构简 单、爱应产物不需婪荐分离答优势，被认为怒最有前途的太阳能制氢技术之 一。 Ti02被公汲为是最遁合的光阳极材料，僵其3+2eV的祭带宽度使太阳能剥 用效率低，阻碍了光电化学电池披术的应用。通过向TiO：中掺杂离子形成燃溶 体结构，可以改藩Ti02光吸收性能，提高太阳能利用效率，推进光电化学电池 豹实用化。 本文在阐述了光电化学电池工作原理及存在的问题的鏊础上，建立了一套 完整的光电化学电池系统，并结合XRD、TEM、吸收光谱等测试手段，对光阳极 材料性熊进行了研究。 本文首先对纯Ti02的性能进行了研究，结果袭盟：在短波隧，锐钛矿Ti02 具有很强的光响应，但在长波区光响应很弱：光电极Ti02膜层膜厚均匀：光电 极Ti02膜鼷的厚度对于光电压有缀大的影口虮 针对Ti02太阳能利用效率低的阚题，本文利用溶胶——凝胶法合成了弧，． 。Fe。O：和TilHxV。02固溶体并对其性能进行了研究，通过与纯Ti02电极性能遴{亍 比较，终暴发现： 在热处理湿度为500。C时，向Ti。2中掺杂＆或V，当＆数含量小予等予 3％，V的含量小于等于7％时，能够形成均匀的圄溶体结构，母致材料在长波 区的光吸收性能爝强，羹含萋越麓增强程度越大，蠢光电极工l乍电压会照卷掺 杂离子含量躲增加恧隆低；当Fe食爨大于3％，V含量大予7％时，无法全帮 形成固溶体结构，多余的离子会极出产生毅相，这时材料可能存在P—n共存蜒 现象。 采媛900。C对掺絷Ti02进嚣热处疆会导致Ti02基痰鑫型转变光毫压惫剩下 降，热处理滠度或Ti02基质照型对于可掺杂浓渡具骞一定既影赡。 关键溺Ti02；露滚髂；掺；掺V AbstractHydrogen Abstract Hydrogen is widely considered to be the best clean fuel of the future．It is an ideal plan for hydrogen generation using scarees of solar energy for water decomposition。 It is argued that PEC(photo—electrochemical cell)technology is the most promising technology for hydrogen production owing to several reasons：PEC technology is environmentally safe，with no undesirable byproducts；PEC technology is relatively uncomplicated；Hydrogen and oxygen are evolved separately at the cathode and anode． Tic2 was identified as the best candidate for the photo-anode．However，owing to its band gap is 3．2eV which is too high that only a怒w part of the solar energy earl be available for conversion，SO the application of PEC is limited．It Was shown that light absorption of Ti02 may be enhanced through doping with ions and producing solid— solutions，which may increase the conversion efficiency and advance the application ofPEC． In the thesis，the principle of the PEC and the problem of which existed were reviewed，and then an experimental system of PEC was set up．The performance of anode material was studied on the PEC system，by analyzing the XRD，TEM and absorption spectrum ofwhich