含有机氟工业废水处理工艺研究-环境工程专业论文.docxVIP

含有机氟工业废水处理工艺研究摘要 含有机氟工业废水处理工艺研究 摘要 某公司生产氟橡胶、塑料工艺过程中会产生大量的有机氟废水，需进行处 理以迭标排放，因此予2001年4月委托问济大学环境科学与工程学院，对其废 水进行研究、试验，力图寻求一套技术合理、经济可行的处理工艺，最终实现达 标排放。本课题通过实验室的试验研究，完成了试验目标．f=睡主要结论如下： 铁还原中和混凝沉淀预处理工艺可以大大提高水质：曝气条件下的预处理 效果较不曝气的效果好，铁刨花还原时间为7h时，COD。，的去除率分别为35．75 和27％，铁刨花还原冲和混凝沉淀工艺可提高废水的可生化性，出水B／C由0．07 提高到O．28，pH由3．7提高到4．96；以硫酸亚铁为混凝剂，直接进行混凝沉淀 试验，当用爨250mg／L时，COD。去除率仅为10％，铁俐花还原一中和混凝沉淀 COD。去除率为35．75％，铁刨花还原-中和混凝沉淀工艺作为预处理工芑是切实 可行的； 好氧反应处理预处理出水，停留时间为36h时，CODe，的去除率仅为20％ 左右，在好氧处理前加厌氧进行预处理怒必要的； 当厌氧反应器的停留时间为15h时，B／C可摊高55％，总磷去除率为35．3％， 羝氮升高15．9％； 厌氧出水进入好氧反应器，停留时闻为36h时，高水氨氮、BODs、pH均 醴达到一级摊放标准，激水COD。，和TP分黼为70和O．85mg／L，去除率分翔为 53．3％和51．3％：乒 ／ 后处理迸行了浠往炭蔽附及混凝沉淀研究。建议采稽FeS04混凝沉淀工艺， 最佳授药量为150mg／L，崮永COD。在60mg／L淤下，Cv-=8．63mg／L，达到一级标 准，出东TP在O．85mg／L之淹，优予二缀标准。 关键词：含氟废水、铁还原．中和混凝沉淀．不完全厌氧j接触氧化 鱼塑塑塑三些堡查竺望三苎竺塞 鱼塑塑塑三些堡查竺望三苎竺塞 ABSTRACT There will be large quantity of fluorine organic waster produced by a company． In order to look for the best process for wastewater treatment and to meet the needs of waster discharge standard in our country,the laboratory scale study has been done systematically in the Key Lab ofPollution Control and Resource Reuse． Acidity of this fluorine—containing wastewater is very high，and the content of toxic organic compounds is also in a high level in this wastewater,which consults in its poor biodegradability．Referring to home and foreign studies on treatment technology,an optimum process is proposed which is combined by ferric aeration reduction process，neutralization，flocculation—precipitation process，incomplete anaerobic process，contact oxidation process and the second flocculation and precipitation． Some conclusion can be reached from the experiment： Quality of the fluorine-containing wastewater can be improved greatly after the wastewater is pretreated by ferric aeration reduction and neutralization by lime． When aeration time is 7 hours and lime is dosed as both neutralizer and coagulant aid，CODcr removal rate is 35．75％．BODJCODc『of the wastewater is increased from O．07