利用几个光周期太赫兹脉冲控制耗散环境中分子定向.pdfVIP

利用几个光周期太赫兹脉冲控制耗散环境中 分子定向 刘勇，李健，于杰，丛书林 大连理工大学物理与光电工程学院，大连 116024 摘要：本文提出利用几个光周期太赫兹脉冲实现耗散环境中分子定向的理论控制方案。通过求 解多能级布洛赫模型下的量子刘维尔方程计算得到数值结果。计算结果表明分子定向度对太赫 兹脉冲的载波相位比较敏感。计算了耗散环境中的一氧化分子在不同压强和温度下的定向和转 动布居。另外，还讨论了纯退相干对分子定向的影响。 关键词：分子定向，太赫兹脉冲，耗散动力学 中图分类号：O561.4 School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 We present a theoretical scheme to achieve the nonadiabatically molecular orientation in dissipative environment by THz few-cycle pulses. Numerical calculations are performed by solving the quantum Liouville equation based on multilevel Bloch model. The molecular orientation degree is sensitive to the carrier-envelope phases of the THz pulses. The orientation and the rotational population of CO molecules in dissipative environment (bath) are computed at different pressures and temperatures. The influence of pure decoherence on the molecular orientation is also discussed. Molecular orientation, THz Pulse, dissipative dynamics Controlling molecular alignment and orientation with laser pulse is an important topic in many research fields such as chemical reaction , high harmonic generation , strong field ：：： ：：： ：：： - 1 - ionization , photoelectron angular distribution , and so on. A strong dc field and a com- bination of dc field and laser pulse have been used to steer adiabatic orientation of molecules with permanent moment in theory and experiment . However, the presence of a dc field may affect the measured results of oriented molecules. Thus, it is of special importance to achieve field-free molecular orientation. Recently, it was demonstrated tha