二萘并噻吩四酮在飞秒激光下的三阶非线性光学性能.PDF

RESEARCH 究报告| 线性光学 二萘并噻吩四酮在飞秒激光下的三 阶非线性光学性能 Third-Order Optical Nonlinearity of Dinaphtho Thiophene Tetrone under Femtosecond Laser Excitation 志彬 余作帅 高建荣 (浙江工业大学精细化工研究所，浙江杭州 310014) Cai Zhibin Yu Zuoshuai Gao Jianrong (Institute of Fine Chemical Industry ，Zheji ang University of Technology ，Hangzhou ，Zhej iang 310014 ，China) 摘 要 ，用 1 合成了化合物二萘并[2 ，3 -b ：2 ，3 -d]噻吩-5 ，7 ，12 ，13- 四酮 IR ，H NMR 和元素分析表征了其结 构。采用波长为800 nm ，脉宽为80 fs 的钛宝石飞秒激光，运用简并四波混频(DFWM)法，研究了化合 物在非共振状态下的三阶非线性光学(NLO)性能。三阶非线性光学极化率为2 .73伊10-13 esu ，非线性折 射率为5.03伊10-12 esu ，分子二阶超极化率为2.85 伊10-31 esu ，响应时间为86 fs 。分析了化合物的分子结 构对三阶非线性光学性能的影响。结果表明此化合物具有潜 的非线性光学应用。 关 键 词 ； ； ； 非线性光学 简并四波混频 二萘并噻吩四酮 三阶非线性光学性能 Abstract The compound dinaphtho [2，3 -b:2 ，3 -d] thiophene -5，7 ，12，13 -tetrone was synthesized and 1 characterized by IR，H NMR and elemental analysis. By using Ti 颐Sapphire femtosecond laser (wavelength of 800 nm，pulse width of 80 fs) ，the off -resonant third-order optical nonlinearity of the compound was measured with degenerate four -wave mixing (DFWM) technique. The third -order nonlinear optical(NLO) susceptibility was 2.73伊10-13 esu. The nonlinear refractive index was 5.03伊10-12 esu. The second-order hyperpolarizability of the molecule was 2.85伊10-31 esu. The response time was 86 fs. The influence of the molecular structure on the third -order optical nonlinearity was analyzed. These results show that this compound has potential nonlinear optical applications. Key words nonlinear optics ；degenerate four -wave mixing；dinaphtho thiophene tetrone；third -order nonlinear