CWPO催化剂的制备及对直接紫D-BL染料废水的脱色-中国环境科学.PDFVIP

中国环境科学 2010,30(9) ：1213~1218 China Environmental Science CWPO 催化剂的制备及对直接紫 D-BL 染料废水的脱色 * 卢堂俊,李剑超 ,孙洪霞,张爱霞,张晓伟 (陕西师范大学旅游与环境学院,陕西 西安 710062) 摘要：通过混合浸渍焙烧法制备一类载 Cu-La-Mo 沸石催化材料(Z/CLM),并通过静态和动态试验研究 Z/CLM 材料 CWPO 法中对直接 紫 D-BL 模拟染料废水的脱色效果.结果表明,制备 Z/CLM 材料的最佳条件为采用 60~80 目的天然沸石作为载体浸渍铜、镧和钼的混合盐 溶液, 600℃焙烧 0.5h;在静态试验中,当 pH 7.10,H O 为 8.33mL/L 时,直接紫 D-BL 的去除率达 95.15%,染料废水的温度和 NaCl 浓度 2 2 对去除效果有促进作用;且通过动态流化床实验可得 Z/CLM 材料对直接紫 D-BL 的去除能力为 37.82mg/g. 关键词：Cu-La-Mo 沸石催化剂；浸渍焙烧；H O ；直接紫 D-BL ；催化氧化 2 2 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2010)09-1213-06 Synthesis and performance of a novel catalyst applied to the CWPO decolorization of direct blending purple (D-BL) on wastewater. LU Tang-jun, LI Jian-chao, SUN Hong-xia, ZHANG Ai-xia, ZHANG Xiao-wei (College of Tourism and Environment, Shaanxi Normal University, Xi’an 710062, China). China Environmental Science, 2010,30(9)：1213~1218 Abstract ：A novel kind of Cu-La-Mo zeolite catalyst (Z/CLM) was prepared with impregnation and calcination hybrid method. A series of static and dynamic experiments was carried out to investigate the catalytic capability of prepared Z/CLM catalyst in the decolorization reaction, and direct blending purple D-BL was selected as target reactant. The experimental results gave out the optimum catalyst preparation conditions as, zeolite particle size of 60~80 mesh, calcination of 600℃ and 0.5h. In the static tests, the highest direct blending purple D-BL decolorization percentage was about 95.15% under the optimum condition, H O 8.33mL/L, pH 7.10. Further experiments revealed that the increase of 2 2 the temperature and the NaCl