固体微粒对气液传质性能的影响及DNS酸的合成工艺改进-化学工程专业论文.docxVIP

摘要常规的气一液一固三相流体系传质机理的研究主要是以静止膜理论或渗透理论 摘要 常规的气一液一固三相流体系传质机理的研究主要是以静止膜理论或渗透理论 为基础，无法准确、真实的反映多相流传质现象的本质。本文以含有活性炭微粒的 丙烷一水三相体系为研究对象，以表面更新理论为出发点，建立了在所选择的特定 反应动力学条件下的气一液一固的传质模型，导出了非稳态非均相传质微分方稷， 求出了传质增强因子E的数学解析解，并在此基础上，分析了固体微粒对气液传 质性能的影响机理，探讨了不同固含率s，微粒直径磊对传质增强因子E的影 响。 以所得的气一液一固三相体系传质模型为指导，对传统的对硝基甲苯邻磺酸 (NTS酸)空气氧化合成制备4,4’．二硝基二苯乙烯一2，2’一二磺酸(DNS酸)的 工艺进行了考察。研究了在反应混合物中加入固体微粒对反应气液传质效果、产品 收率、反应时间的影响。一系列对比实验的结果从定性的角度说明了：本文所建的 传质模型较好的反映了气一液一同三相体系传质规律。与传统工艺相比，加入适量 的固体微粒后，该合成反应在反应时间、产品收率、成本消耗等方面都得到了明显 的改善。 关键词：气液固三相秣表面更薪超g论固体，钕粒 传质模塾 非均相DNS酸 。 ＼。 ABSTRACTFormer ABSTRACT Former researches of mass transfer of gas—liquid—solid three—phase systems mostly bases on stagnant film theory and penetration theory，seldom investigation is based on surface·renew theory．Accordingly，the rule of mass transfer of gas—liquid—solid three． phase systems can’t be explained exactly by those investigations．In this paper，the mass transfer of propane-water-active carbon systems has been investigated，and the effect of solid fine particles on gas—liquid mass transfer rates has been studied based on surface— renew theory．Under the selected particular kinetic conditions，the mass transfer mechanism is analyzed and a heterogeneous mathematical model based on surface—lenew theory is proposed．The heterogeneous mass transfer differential equation is deduced， then the analytical solution ofmass transfer enhancement factor E is obtained．The effects of solid holdups s and particles’diameter d。on E are also discussed． At the first time，solid fine particles are used in the traditional dinitrostilbene disulfonic acid(DNS)which is synthesized by the air oxidation of 4-nitrotoluene-2一 sulfonic acid(NTS)production in this article．The effects of solid fine particles on yield of DNS and reaction time ale studied．The compared experimental results proved the correctness of set-up models qualitatively．Compared with the old processes，the yield of DNS is improved and reaction time is shortened in the new processes．The results indicated t