微细腔内甲烷湿空气低温重整特性热力学分析-物理化学学报.PDF

理化学学报(Wuli Huaxue Xuebao) November A cta Phys. Chim. Sin., 2010, 26(11) ：2899-2906 2899 [Article] 微细腔内甲烷湿空气低温重整特性热力学分析 景煜 赵柳洁 (重庆大学动力工程学院, 重庆 400044) 摘要： 从理论上探讨低温(小于973 K)、压力、空碳比及水碳比对重整特性及甲烷转化率的影响, 以及各参数的 合理取值范围; 同时, 对甲烷自热重整系统与无氧重整系统进行了性能对比. 研究结果表明: 微细腔在温 大于 633 K, 反应压力小于0.10 MPa, 空碳(摩尔) 比为2.0 以及水碳摩尔比在1.0-2.5 之间有利于甲烷自热重整反应的 发生; 自热重整与无氧重整体系相比, 当甲烷质量流量一定时, 有氧系统可以在较低的水碳比和较低的温度条件 下获得较高的甲烷转化率和氢气产量. 关键词： 微细腔; 低温; 自热重整; 热力学分析; 无氧系统; 对比 中图分类号： O642 Thermodynamic Analysis of Low Temperature Methane Wet Air Reforming in a Microcombustor RAN Jing Yu ZHAO Liu Jie (College of Thermal Power Engineering, Chongqing University, Chongqing 400044, P.R.China) Abstract ： We studied the effects of reaction pressure, molar ratios of air to methane and steam to methane on the reforming process at temperatures below 973 K theoretically. Their reasonable ranges were also studied. We also compared the performance of a methane autothermal reforming system and a non oxygen system. Results show that methane autothermal reforming occurs much more easily at temperatures above 633 K, reaction pressures below 0.10 MPa, a molar ratio of air to methane of 2.0, and a molar ratio of steam to methane between 1.0 and 2.5. At a definite methane mass flow, a higher methane conversion rate and hydrogen yield can be obtained at lower temperatures and in lesser steam to methane ratio in an autothermal reforming system compared with a non oxygen system. Key Words ： Micro combustor; Low tem