熔盐电解法制备Al-Cu中间合金廖春发罗林生王旭江西理工大学.DOCVIP

熔盐电解法制备Al-Cu中间合金 廖春发，罗林生，王旭 （江西理工大学 冶金与化学工程学院，江西 赣州 341000） 摘 要：以Na3AlF6-AlF3-MgF2-LiF为电解质，Al2O3、CuO为原料，对熔盐电解共沉积制备Al-Cu中间合金进行了研究，采用扫描电子显微镜（SEM）、能谱（EDS）及X衍射（XRD）分析合金表征形貌及元素分布。结果表明：施加外电压在2.6~3.5 V之间，合金形成速率随电压的增加先增加后降低，施加外电压在3.3V时，合金形成速率可达最大值；温度为895~955 ℃之间，合金的形成速率随温度升高先增加后降低，温度为935℃时可达最大值；恒压3.3 V，温度为935 ℃，可制得Cu质量含量为11.51 %和获得纯度达97.2 %的Al-Cu合金，且合金中的铜与铝合金化过程中主要是以环状的Al2Cu相分布在晶界中；通过XRD分析得到合金中Cu主要是以Al2Cu相存在于合金组织中。 关键词：熔盐电解；氧化铜；Al-Cu中间合金；形成速率 中图分类号: 文献标志码: Study on Preparation of Al -Cu Intermediate Alloy by Molten-salt electrolytic LIAO Chun-fa, LUO Lin-sheng,WANG Xu (School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China) Abstract: Based on Na3AlF6-AlF3-MgF2-LiF as electrolyte and treat Al2O3、CuO as raw materials, this paper adopts Molten-salt?electrolytic to prepare middle Al-Cu alloy by coelectrodeposition and We analysed its alloy morphologies and elemental distributions by SEM , EDS and XRD. The results showed : with the increasing of the voltage ,the alloy formation rate increases first and then decreases at the applied outer?voltage?between?in?2.6~3.5 V, the rate up to a maximum value at 3.3 V. With the increasing of the temperature, the alloy formation rate increases first and then decreases at the temperature between 895~955 ℃, the rate up to a maximum value at 935 ℃. The content of Cu in alloy is about 11.51 wt.%，and purity of Al-Cu alloy can achieve 97.2% at the constant voltage of 3.3 V and the temperature of 935 ℃，copper and aluminum alloys present rings Al2Cu phase diffuse distribution in the grain boundary in the alloying process.. Alloy is obtained by X-ray diffraction (XRD) analysis of Cu mainly present Al2Cu phase in the alloy. Key words: Molten-salt?electrolytic;Copper oxide ;Al-Cu Intermediate Alloy;The rate of formation 0 引言 Al-Cu系合金是应用较早的一种高强韧性的铝合金材料之一，由于析出的CuAl2相使得铝铜合金具有良好的耐高温、机械性能、较高的强度、良好的塑性、良好的室温及高温性能等优势而引起人们注意[1-4]，在汽车、航空、航天等领域有广泛的潜在应用前景[5]。目前铝铜合金