减缩剂外涂对水泥基材料性能的影响-硅酸盐学报.PDF

第36 卷第7 期 侯东伟 等：基于早期变形特征的混凝土凝结时间的确定 · 1085 · 第37 卷第7 期 硅 酸 盐 学 报 Vol. 37 ，No. 7 2 0 0 9 年 7 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY J u l y ，2 0 0 9 减缩剂外涂对水泥基材料性能的影响 1 2,3 2 2 王 智 ，乔 墩 ，钱觉时 ，石 亮 (1. 重庆大学化学化工学院，重庆 400044 ；2. 重庆大学材料科学与工程学院，重庆 400045 ；3. 重庆市公路局，重庆 401147) 摘 要：对比研究了减缩剂内掺和外涂对砂浆收缩、抗裂及力学性能的影响。结果表明：减缩剂外涂对砂浆试件有比较明显的减缩效果；减缩剂外涂 的溶液浓度越高，减缩效果越好，适宜浓度为50%；相比内掺，减缩剂外涂可提高砂浆的抗折强度和抗压强度，提高砂浆抗裂性能，开裂面积下降了 35%；减缩剂外涂增加水泥石中C–S–H 凝胶及钙矾石的生成量，减少了水泥石中20～50 nm 毛细孔的数量。 关键词：减缩剂；外涂；收缩；抗裂性能；强度 中图分类号：TU528.042 文献标志码：A 文章编号：0454–5648(2009)07–1085–07 EFFECT OF COATING WITH SHRINKAGE REDUCING AGENTS ON THE PROPERTIES OF CEMENT-BASED MATERIALS WANG Zhi1 2,3 2 2 ，QIAO Dun ，QIAN Jueshi ，SHI Liang (1. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044; 2. College of Material Science and Engineering, Chongqing University, Chongqing 400045; 3. Chongqing Bureau of Highway Administration, Chongqing 401147, China) Abstract: The effect of mixing and coating with shrinkage reducing agents (SRA) on shrinkage, crack resistance and mechanical properties of mortar were comparatively investigated. The results show that coating with SRA can obviously reduce the shrinkage of the mortar. Coating with higher concentration solutions of SRA results in a greater shrinkage reducing ratio; the optimal concentration is 50%. Compared with mixing with SRA, coating with SRA enhances the flexural strength and compressive strength of the mortar.