几种纳米复合薄膜的制备 表征及应用研究-化学、分析化学专业论文.docx

陈扬 陈扬 兰州大学博上学位论文 中文摘要 曼增强效应；经过十二硫醇的化学修饰，树枝纳米Ag／Cu膜表面呈现超疏水特 性及低的接触角滞后性能。 4．采用无电沉积的方法，分别以Ag和Pd催化晶籽层沉积Pd／Ag薄膜。薄 膜的形态和组成分别用原子力显微镜(AFM)和X光电子能谱(xPs)表征。实验 表明Ag晶籽不能催化Pd纳米粒子的沉积，得到的只是纯Ag，而非Pd／Ag合金； Pd晶籽却能催化Ag纳米粒子的沉积，得到的是Pd／Ag合金。同时，Ag纳米粒 子在Pd晶籽上的沉积速率比在Ag晶籽上的快得多。以所制得的薄膜为工作电 极，在暗态条件下测其阴极极化曲线，考察了析氢反应情况。 关键词：纳米复合薄膜；电泳沉积；无电沉积；光催化降解；电子顺磁共振(EPR)； 表面增强拉曼；超疏水性能 Ⅱ 陈扬 陈扬 兰州大学博上学位论文 Abstract In this thesis，Ti02／GE，dendritic Ag／Cu and Pd／Ag nano composite thin films ar e prepared by electrochemical or electroless techniques．The morphology and composition of the films are studied comparatively by using XRD，SEM，AFM and XPS．Promising multifunctional applications are obtained including photocatalytic degradation,strong surface-enhanced Raman scattering(SERS)enhancement and superhydrophobic application．The main contents are described as follows： 1．Nano-Ti02 particles were immobilized on graphite electrode(GE)and indium-tin oxide coated glass(ITO)using electrophoretic deposition,respectively． The obtained Ti02／GE and Zi02／ITO film electrodes were characterized by X·ray diffraction(XRD)，field emission scanning electron microscopy(FE—SEM)and anodic photocurrent response test．It Was found that Ti02／GE electrode had much higher photocurrent and more effectively reduced the recombination rate of the photo—induced electron-hole pairs，compared with Ti02／ITO electrode．The photocatalytic activity of TiOffGE Was higher than that of Ti02／ITO for the photocatalytic degradation of acid red G． 2．Formaldehyde Was degradated with photo—catalysis by Ti02 nanoparticles and 2-methyl-2一nitro—propane(MNP)Was used as a spin trap(ST)．The radical intermediates in the process of reaction were studied and a new spin adducts(ST-R) Was obtained．The results of Electron Paramagnetic resonance(EPR)indicated that intermediates of formaldehyde degradation in aqueous solution were。CH(OH)2．And a new degradation mechanism was proposed． 3．Hierarchical and well—defined Ag dendrites were obtained by the reaction between copper m