甲苯甲醇烷基化催化剂的改性及反应性能研究-化学工程专业论文.docxVIP

甲苯甲醇烷基化反应催化剂改性及反应性能研究Alkylation 甲苯甲醇烷基化反应催化剂改性及反应性能研究 Alkylation of Toluene with Methanol over Modified catalysts Ab stract With the development ofpolyester industry，the dermnd ofpara·xylene has been increased quickly SO that the production can’t meet iL Presently para-xylene is generated through naphtha cracking，catalytic reforming,coke by-products，et a1．Conventional technology of para—xylene producing has meet challenges since the decline ofoil resourees．So its urgent to deve lop neW effic ient method for para—xylene．Para-xylene obtained by to luene alkyhtion with methanol alleviat the excess of rnethanot It’S a Project of lligh practicability a耐 promising market．It’S necessary to research highly efficient catalysts for reaction of toluene alkyhtion with methano 1．ZSM一5 is a widely used catalyst for the reaction,and catalytic performance is closely related to morphology,crystalline size，crystallinity,SFAL modification reagents，adding order of modification reagents of catalysts． Whether a technology applied in industry depend on its economic benefits．Firstly we adopted industrial reagents modified catalysts for the reaction of benzene alkylation with methan01．It was found that with modified steps increasing the conversion of toluene Was dropping硒m 13．4％to 10．7％，while the selectivity of pam—xylem Was increasing from 33．2％to 87．7％．There is no significant difference in conversion of toluene on induslrial reagents and analytical reagents modified catalysts，but selectivity of pare·xylene is little lower around l％一4％on the former．Next,we applied Fe modified catalyst under a flow of N2 for the reaction to cut costs．Compared ferric nitrate．缸r论citrate，ammonium ferric citrate modified catalysts．Catalytic performance of ferric nitrate modified catalysts is the best,while ammonium ferric citrate modified catalysts is the last．We found that utilization of methan01 was very low for the reaction．Methanol is an active reactant,it tends to produce light hydrocarbon,SO we s